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| 1 | Simulation and study on mitigation measures of frequent subsynchronous oscillation with low amplitude at multi-power plants显示文摘Subsynchronous oscillation (SSO) with low amplitude that exceeds cumulative fatigue threshold of the generator shaft frequently could significantly reduce the shaft's service life, which is a new SSO problem that emerges in recent years. According to the real recording oscillograph, the basic reason for frequently over-threshold SSO with low amplitude at multi-power plants was analyzed based on Hulunbuir League system. The sensitivities of the electrical damping to the main electrical parameters in the contributing loop of subsynchronous torsional interaction were calculated. Based on the sensitivities, a simulation method was presented, which was used to excite the same oscillation as the actual case by exerting disturbance on the firing angle. The limitation of wide-band and narrow-band supplementary subsynchronous damping controller (SSDC) for mitigating this kind of SSO was analyzed based on the electromagnetic transient simulation model of Hulunbuir League system. The difference of supplementary excitation damping controller (SEDC) and parallel-form FACTS connected to the generator terminal was compared from the aspects of response time and the ability of damping torque supplying. The analysis indicates that their response time is similar but FACTS has stronger ability of damping torque supplying than SEDC. Time-domain simulation method was used to compare the mitigation effects of SEDC, static var compensator (SVC) and static synchronous compensator (STATCOM). Considering the mitigation effect, the floor space limit of the power plant and so on, STATCOM was considered as the best mitigation measure. A control strategy of cascaded STATCOM for engineering application was presented and the capacity for SSO mitigation as well as output characteristics was analyzed. The analysis indicates that STATCOM using the proposed control strategy has better mitigation effect and output characteristics with smaller capacity. | XIAO XiangNing ZHANG Jian GAO BenFeng WU YunSheng LUO Chao GUO ChunLin YANG Lin | 2013 | Science China(Technological Sciences)2013，56，6： | 13 |
| 2 | Tomato lncRNA23468 functions as a competing endogenous RNA to modulate NBS-LRR genes by decoying miR482b in the tomato-Phytophthora infestans interaction显示文摘Our previous studies indicated that tomato miR482b could negatively regulate the resistance of tomato to Phytophthora infestans and the expression of miR482b was decreased after inoculation with P.infestans.However,the mechanism by which the accumulation of miR482b is suppressed remains unclear.In this study,we wrote a program to identify 89 long noncoding RNA(lncRNA)-originated endogenous target mimics(eTMs)for 46 miRNAs from our RNA-Seq data.Three tomato lncRNAs,lncRNA23468,lncRNA01308 and lncRNA13262,contained conserved eTM sites for miR482b.When lncRNA23468 was overexpressed in tomato,miR482b expression was significantly decreased,and the expression of the target genes,NBS-LRRs,was significantly increased,resulting in enhanced resistance to P.infestans.Silencing lncRNA23468 in tomato led to the increased accumulation of miR482b and decreased accumulation of NBS-LRRs,as well as reduced resistance to P.infestans.In addition,the accumulation of both miR482b and NBS-LRRs was not significantly changed in tomato plants that overexpressed lncRNA23468 with a mutated eTM site.Based on the VIGS system,a target gene of miR482b,Solyc02g036270.2,was silenced.The disease symptoms of the VIGS-Solyc02g036270.2 tomato plants were in accordance with those of tomato plants in which lncRNA23468 was silenced after inoculation with P.infestans.More severe disease symptoms were found in the modified plants than in the control plants.Our results demonstrate that lncRNAs functioning as eTMs may modulate the effects of miRNAs in tomato and provide insight into how the lncRNA23468-miR482b-NBS-LRR module regulates tomato resistance to P.infestans. | Ning Jiang Jun Cui Yunsheng Shi Guanglei Yang Xiaoxu Zhou Xinxin Hou Jun Meng Yushi Luan | 2019 | Horticulture Research2019，6，1： | 12 |
| 3 | Characteristics of fecal microbiota in non-alcoholic fatty liver disease patients显示文摘This study was designed to investigate the gut microbiota of patients with non-alcoholic fatty liver disease. The inclusive and exclusive criteria for NAFLD patients and healthy subjects were formulated, and detailed clinical data were collected. The genomic DNA of stool samples were extracted for 16 S r DNA sequencing, and the amplified V4-region was sequenced on the Illumina Miseq platform. Metastats analysis was performed to identify the differential taxa between the groups. Redundancy analysis was used to evaluate the association between gut microbial structure and clinical variables. Thirty NAFLD patients and37 healthy controls were involved. The 16 S r DNA sequencing showed that there was a dramatic variability of the fecal microbiota among all the individuals. Metastats analysis identified eight families and 12 genera with significant differences between the two groups. When some clinical parameters, such as waist-to-hip ratio(WHR) and homeostasis model assessment of insulin resistance(HOMA-IR), were enrolled in Redundancy analysis, the distribution of the two group of samples was obviously changed. The compositional shifts in fecal bacterial communities of NAFLD patients from the healthy controls were mainly at family or genus levels. According to our Redundancy analysis, insulin resistance and obesity might be closely related to both NAFLD phenotype and intestinal microecology. | Fan Li Gang Sun Zikai Wang Wenming Wu He Guo Lihua Peng Lili Wu Xu Guo Yunsheng Yang | 2018 | Science China(Life Sciences)2018，61，7： | 9 |
| 4 | Host–guest materials with room temperature phosphorescence:Tunable emission color and thermal printing patterns显示文摘The research of purely organic materials with long afterglow has drawn more and more attention,especially for those with stimulus‐response characteristic.So far,this kind of material is really very scarce and their performance is not good enough.In this study,we successfully developed an efficient heatingresponsive room‐temperature phosphorescence material with phosphorescence efficiency and lifetime up to 13.4%and 2.08 s through the simple host–guest doping strategy.Further on,by introducing the additional energy acceptor of fluorescein with concentration‐dependent emission to construct ternary doping systems,the afterglow color was extended from blue to yellow.Accordingly,the multicolor thermal printings have been easily realized,showing the great practical application prospects. | Yunsheng Wang Jie Yang Yanxiang Gong Manman Fang Zhen Li Ben Zhong Tang | 2020 | SmartMat2020，1，1： | 8 |
| 5 | Timing of transplantation of autologous bone marrow derived mesenchymal stem cells for treating myocardial infarction显示文摘It is still unclear whether the timing of intracoronary stem cell therapy affects the therapeutic response in patients with myocardial infarction.The natural course of healing the infarction and the presence of putative homing signals within the damaged myocardium appear to favor cell engraftment during the transendothelial passage in the early days after reperfusion.However,the adverse inflammatory environment,with its high oxidative stress,might be deleterious if cells are administered too early after reperfusion.Here we highlight several aspects of the timing of intracoronary stem cell therapy.Our results showed that transplantation of bone marrow mesenchymal stem cells at 2 4 weeks after myocardial infarction is more favorable for reduction of the scar area,inhibition of left ventricular remodeling,and recovery of heart function.Coronary injection of autologous bone marrow mesenchymal stem cells at 2 4 weeks after acute myocardial infarction is safe and does not increase the incidence of complications. | CHEN YiHuan TENG XiaoMei CHEN WeiQian YANG JunJie YANG ZiYing YU YunSheng SHEN ZhenYa | 2014 | Science China(Life Sciences)2014，57，2： | 7 |
| 6 | Geochronology and Geochemistry of Metallogenetic Porphyry Bodies from the Nongping Au-Cu Deposit in the Eastern Yanbian Area, NE China: Implications for Metallogenic Environment显示文摘The metallogenetic porphyry bodies in the Nongping Au-Cu deposit, in the eastern Yanbian area, mainly include porphyritic granodiorite and biotite granodiorite porphyry. They are featured with high silicon and enrichment in sodium, and classified into sodic rocks of low-K tholeiitic basalt series. Except slightly low Sr content, the rock basically has the geochemical characteristics of the adakite: relatively high A12O3 content, relatively low MgO content, depletion in Y and Yb; relative enrichment in large ion lithophile elements (LILEs) and light rare-earth elements (LREEs), relatively low content of high field strength elements (HFSEs); positive Eu anomaly or weak negative Eu anomaly. In situ zircon dating technology LA-MC-ICP-MS was used to conduct single-grain zircon dating of biotite granodiorite porphyry, and the results show that the age of metallogenetic porphyry body is 100.04±0.88 Ma, indicating that the porphyry bodies were emplaced in the late Cretaceous period. According to the regional tectonic setting and the comparison with the same kind of deposits, we think that the metallogenetic porphyry bodies in the Nongping Au-Cu deposit have a close genetic connection with the subduction of the Pacific plate in the late Yanshanian period. The adakitic magma generated from partial melting of the subducting plate has high formation temperature, high oxygen fugacity, and volatile constituents' enrichment, so it is helpful for enrichment of metallogenetic elements and plays an important role in the formation of porphyry Au-Cu deposits in this region. | REN Yunsheng JU Nan ZHAO Hualei WANG Hui HOU Kejun LIU Shen | 2012 | Acta Geologica Sinica(English Edition)2012，86，3： | 7 |
| 7 | Early Hydration and Setting Process of Fly Ash-blended Cement Paste under Different Curing Temperatures显示文摘A specially developed ultrasonic measurement apparatus (UMA) was used to in situ monitor the setting process of fly ash blended cement paste. Combined with the results of Vicat Needle tests, isothermal calorimetric measurement, XRD analysis, SEM morphology and compressive test, the influence of curing temperature (20, 40, 60, and 90 ℃) and fly ash content (0,10%, 20% and 30%) on the setting and hydration process of fly ash blended cement paste was analyzed. The results show that setting and hardening process of fly ash blended cement paste at elevated temperature can be clearly identified into three stages including dormant stage, acceleration stage and deceleration stage. The increasing of curing temperature greatly accelerates the setting and hardening process. However, the content of fly ash does not have significant effect on the setting in condition of 90 ℃. Besides, the initial and final setting time of cement paste is correspondent with the time of duration of dormant stage and the time of UPV value is 1500 m/s (T1500), respectively. Thus, the UMA can be used to determine the initial and final setting time of cementitious material under different curing temperatures. The compressive test results indicate that the paste with 20% fly ash presents higher compressive strength than the plain paste at curing temperatures of 90 ℃. Therefore, appropriate amount of fly ash is beneficial for concrete in the high temperature curing conditions. | 张文华 WU Fan ZHANG Yunsheng | 2020 | Journal of Wuhan University of Technology(Materials Science)2020，35，3： | 7 |
| 8 | Attack on Libert et al.'s ID-Based Undeniable Signature Scheme显示文摘 | LI Zichen YAN Yunsheng ZHANG Juanmei | 2008 | Chinese Journal of Electronics2008，17，4： | 7 |
| 9 | Concurrent catalytic removal of typical volatile organic compound mixtures over Au-Pd/α-MnO2 nanotubes显示文摘α-MnO_2 nanotubes and their supported Au-Pd alloy nanocatalysts were prepared using hydrothermal and polyvinyl alcohol-protected reduction methods, respectively. Their catalytic activity for the oxidation of toluene/m-xylene, acetone/ethyl acetate, acetone/m-xylene and ethyl acetate/m-xylene mixtures was evaluated. It was found that the interaction between Au-Pd alloy nanoparticles and α-MnO_2 nanotubes significantly improved the reactivity of lattice oxygen, and the 0.91 wt.% Au0.48 Pd/α-MnO_2 nanotube catalyst outperformed the α-MnO_2 nanotube catalyst in the oxidation of toluene, m-xylene, ethyl acetate and acetone. Over the0.91 wt.% Au0.48 Pd/α-MnO_2 nanotube catalyst,(i) toluene oxidation was greatly inhibited in the toluene/m-xylene mixture, while m-xylene oxidation was not influenced;(ii) acetone and ethyl acetate oxidation suffered a minor impact in the acetone/ethyl acetate mixture; and(iii) m-xylene oxidation was enhanced whereas the oxidation of the oxygenated VOCs(volatile organic compounds) was suppressed in the acetone/m-xylene or ethyl acetate/m-xylene mixtures. The competitive adsorption of these typical VOCs on the catalyst surface induced an inhibitive effect on their oxidation, and increasing the temperature favored the oxidation of the VOCs. The mixed VOCs could be completely oxidized into CO_2 and H_2 O below 320°C at a space velocity of 40,000 m L/(g·hr). The 0.91 wt.% Au0.48 Pd/α-MnO_2 nanotube catalyst exhibited high catalytic stability as well as good tolerance to water vapor and CO_2 in the oxidation of the VOC mixtures. Thus, the α-MnO_2 nanotube-supported noble metal alloy catalysts hold promise for the efficient elimination of VOC mixtures. | Yunsheng Xia Lu Xia Yuxi Liu Tao Yang Jiguang Deng Hongxing Dai | 2018 | Journal of Environmental Sciences2018，30，2： | 7 |
| 10 | Adaptive Resource Allocation with SVM-based Multi-hop Video Packet Delay Bound Violation Modeling显示文摘 | ZHANG Yunsheng ZHANG Yongfei SUN Shixin QIN Shiyin HE Zhihai | 2011 | Chinese Journal of Electronics2011，20，2： | 7 |
| 11 | Slope Seismic Response Monitoring on the Aftershocks of the Wenchuan Earthquake in the Mianzhu Section显示文摘Previous investigations have shown that the seismic response of slopes during the Wenchuan earthquake was highly variable.The present study tries to give an answer to the question:Which are the main factors affecting the seismic response degree of slopes? With the support of the China Geological Survey Bureau,we set 3 monitoring sections in Jiulong slope,Mianzhu city,China with the aim to record the site response of the slope during the aftershocks of the Wenchuan earthquake.After the Wenchuan earthquake,which happened on 12 May 2008,30 aftershocks have been recorded in these monitoring points.We analyzed 11 records,with magnitudes ranging from ML = 4.6 to ML = 3.1.The amplification factors of the horizontal compound PGA and 3D compound PGA have been determined for the 3 points at different elevations on the slope.Results showed that the dynamic response of the slope on the earthquake was controlled by factors such as topography and the thickness of the Quaternary overburden. | WANG Yunsheng LUO Yonghong WANG Fuhai WANG Dong MA Xiao LI Shun DENG Xi | 2012 | Journal of Mountain Science2012，9，4： | 6 |
| 12 | Vertical Distribution Characteristics of PM2.5 Observed by a Mobile Vehicle Lidar in Tianjin, China in 2016显示文摘We present mobile vehicle lidar observations in Tianjin, China during the spring, summer, and winter of 2016. Mobile observations were carried out along the city border road of Tianjin to obtain the vertical distribution characteristics of PM_(2.5). Hygroscopic growth was not considered since relative humidity was less than 60% during the observation experiments. PM_(2.5) profile was obtained with the linear regression equation between the particle extinction coefficient and PM_(2.5) mass concentration. In spring, the vertical distribution of PM_(2.5) exhibited a hierarchical structure. In addition to a layer of particles that gathered near the ground, a portion of particles floated at 0.6–2.5-km height. In summer and winter, the fine particles basically gathered below 1 km near the ground. In spring and summer, the concentration of fine particles in the south was higher than that in the north because of the influence of south wind. In winter, the distribution of fine particles was opposite to that measured during spring and summer. High concentrations of PM_(2.5) were observed in the rural areas of North Tianjin with a maximum of 350 μg m–3 on 13 December2016. It is shown that industrial and ship emissions in spring and summer and coal combustion in winter were the major sources of fine particles that polluted Tianjin. The results provide insights into the mechanisms of haze formation and the effects of meteorological conditions during haze–fog pollution episodes in the Tianjin area. | Lihui LYU Yunsheng DONG Tianshu ZHANG Cheng LIU Wenqing LIU Zhouqing XIE Yan XIANG Yi ZHANG Zhenyi CHEN Guangqiang FAN Leibo ZHANG Yang LIU Yuchen SHI Xiaowen SHU | 2018 | Journal of Meteorological Research2018，32，1： | 5 |
| 13 | Comparison of Two Air Pollution Episodes over Northeast China in Winter 2016/17 Using Ground-Based Lidar显示文摘This study analyzes and compares aerosol properties and meteorological conditions during two air pollution episodes in 19–22(E1) and 25–26(E2) December 2016 in Northeast China. The visibility, particulate matter(PM) mass concentration, and surface meteorological observations were examined, together with the planetary boundary layer(PBL) properties and vertical profiles of aerosol extinction coefficient and volume depolarization ratio that were measured by a ground-based lidar in Shenyang of Liaoning Province, China during December 2016–January 2017.Results suggest that the low PBL height led to poor pollution dilution in E1, while the high PBL accompanied by low visibility in E2 might have been due to cross-regional and vertical air transmission. The PM mass concentration decreased as the PBL height increased in E1 while these two variables were positively correlated in E2. The enhanced winds in E2 diffused the pollutants and contributed largely to the aerosol transport. Strong temperature inversion in E1 resulted in increased PM2.5 and PM10 concentrations, and the winds in E2 favoured the southwesterly transport of aerosols from the North China Plain into the region surrounding Shenyang. The large extinction coefficient was partially attributed to the local pollution under the low PBL with high ground-surface PM mass concentrations in E1,whereas the cross-regional transport of aerosols within a high PBL and the low PM mass concentration near the ground in E2 were associated with severe aerosol extinction at high altitudes. These results may facilitate better understanding of the vertical distribution of aerosol properties during winter pollution events in Northeast China. | Yanjun MA Hujia ZHAO Yunsheng DONG Huizheng CHE Xiaoxiao LI Ye HONG Xiaolan LI Hongbin YANG Yuche LIU Yangfeng WANG Ningwei LIU Cuiyan SUN | 2018 | Journal of Meteorological Research2018，32，2： | 5 |
| 14 | Comparison of mixing layer height inversion algorithms using lidar and a pollution case study in Baoding, China显示文摘Beijing–Tianjin–Hebei area is suffering from atmospheric pollution from a long time. The understanding of the air pollution mechanism is of great importance for officials to design strategies for the environmental governance. Mixing layer height(MLH) is a key factor influencing the diffusion of air pollutants. It plays an important role on the evolution of heavy pollution events. Light detection and ranging(lidar), is an effective remote-sensing tool, which can retrieve high spatial and temporal evolution process within mixing layer(ML), especially the variation of MLH. There are many methods to retrieve MLH, but each method has its own applicable limitations. The Mie-lidar data in Beijing was firstly used to compare three different algorithms which are widely used under different pollution levels.We find that the multi-layer structure near surface may cause errors in the detection of mixing layer. The MLH retrieved based on image edge detection was better than another two methods especially under heavy polluted episode. Then we applied this method to investigate the evolution of the mixing layer height during a pollution episode in December2016. MLH at Gucheng county showed the positive correlation with the concentration of particulate matters during the start of this pollution episode. The elevated pollution level in Gucheng was not associated with MLH's decrease, and the significantly increased particulate matters raised the boundary layer, which trapped the pollutants near the surface. | Xiangguang Ji Cheng Liu Zhouqing Xie Qihou Hu Yunsheng Dong Guangqiang Fan Tianshu Zhang Chengzhi Xing Zhuang Wang Zeeshan Javed Jianguo Liu | 2019 | Journal of Environmental Sciences2019，31，5： | 5 |
| 15 | A High Power 320–356GHz Frequency Multipliers with Schottky Diodes显示文摘A 320–356GHz fixed-tuned frequency doubler is realized with discrete Schottky diodes mounted on 50μm thick quartz substrate. Influence of circuit channel width and thermal dissipation of the diode junctions are discussed for high multiplying efficiency. The doubler circuit is flip-chip mounted on gold electroplated oxygenfree copper film for grounding of RF and DC signals, and better thermal transportation. The whole multiplying circuit is optimized and established in Computer simulation technology(CST) suite. The highest measured multiplying efficiency is 8.0% and its output power is 5.4mW at 328 GHz. The measured typical output power is 4.0mW in 320–356GHz. | YAO Changfei ZHOU Ming LUO Yunsheng | 2016 | Chinese Journal of Electronics2016，25，5： | 5 |
| 16 | Study on Catalytic Alkylation of Benzene with Methanol over ZSM-22 and ZSM-35显示文摘The ZSM-22 and ZSM-35 zeolites were synthesized via the hydrothermal crystallization method. The samples were characterized by XRD, SEM, N_2 adsorption-desorption, NH_3-TPD, TPO, TG, and Raman spectrometry, and the results showed that ZSM-22 and ZSM-35 possessed similar microporous volume and acidity. In the alkylation of benzene with methanol, ZSM-22 and ZSM-35 showed different coke location, coking rate and graphitizing degree. Compared with the industrial ZSM-5, ZSM-22 and ZSM-35 both showed higher selectivity of toluene and xylene(93.63% and 96.50%,respectively) during the alkylation of benzene with methanol, and the selectivity of para-xylene in xylene isomers was51.96% and 41.45%, respectively. Meanwhile, the selectivity of ethylbenzene and C_9^+ aromatics was also lower than that of industrial ZSM-5. | Li Yunsheng Wen Zhenhao Wei Zhenhao Yang Fan Zhu Xuedong | 2017 | China Petroleum Processing & Petrochemical Technology2017，19，4： | 5 |
| 17 | A 5.4mW and 6.1% efficiency fixed-tuned 214GHz frequency doubler with Schottky barrier diodes显示文摘A Y-band frequency doubler is analyzed and designed with GaAs planar Schottky diode,which is flip-chip solded into a 50|xm thick quartz substrate.Diode embedding impedance is found by fullwave analysis with lumped port to model the nonlinear junction for impedance matching without the need of diode equivalent circuit model.All the matching circuit is designed 'on-chip' and the multiplier is self-biasing.To the doubler,a conversion efficiency of 6.1%and output power of 5.4mW are measured at 214 GHz with input power of 88 mW,and the typical measured efficiency is 4.5%in200~225GHz. | 姚常飞 Zhou Ming Luo Yunsheng Kou Yanan Li Jiao | 2015 | High Technology Letters2015，21，1： | 4 |
| 18 | Seismic hazard assessment of the Three Gorges Project显示文摘Seismic monitoring data for the past 50 years in the Three Gorges Reservoir area show that the reservoir head area is a typical weak seismic region with low seismicity before impoundment and that the epicenters were concentrated in the east and west sides of the Zigui Basin,most of which were natural tectonic earthquakes.After impoundment,the seismic activity shifted to the segment between Badong and Zigui along the Yangtze River,mainly within 5 km of the reservoir bank.The seismogenesis was categorized into four types:Karst collapse earthquakes,earthquakes caused by Karst gas explosion,mining tunnel collapse earthquakes,and rock (terrane) slip earthquakes,all of which are related to the lithology,structure,and tectonics of near-surface geological bodies of the area.Compared with the seismicity before impoundment,the seismic frequency increase was remarkable,with most of the magnitudes below Ms2.0.Therefore,the intensity of the earthquakes remained at a low level.On November 22,2008,a magnitude 4.1 earthquake,the largest earthquake recorded since impoundment,occurred in Quyuan Town,Zigui County.The intensity and PGA of reservoir-induced earthquakes are higher than those of tectonic earthquakes with equal magnitude,but the peak intensity of reservoir-induced earthquakes is not likely to go beyond that of the estimated range from earlier studies. | Yao Yunsheng Wang Qiuliang Li Jinggang Shen Xueling Kong Yuyang | 2013 | Geodesy and Geodynamics2013，4，2： | 4 |
| 19 | Metallogenic Mechanism and Tectonic Setting of Tungsten Mineralization in the Yangbishan Deposit in Northeastern China显示文摘The Yangbishan iron–tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of the scheelite show that it formed in a reducing environment and inherited the rare earth element features of the ore-forming fluid. The geochemical characteristics of the gneissic granite associated with the tungsten mineralization show that the magma formed in this reducing environment and originated from the partial melting of metamorphosed shale that contained organic carbon and was enriched with tungsten. In addition, in situ Hf isotopic analysis of zircons from the gneissic granite indicates that they probably originated from the partial melting of a predominantly Paleo–Mesoproterozoic crustal source. According to LA-ICP-MS zircon dating, the Yangbishan orerelated gneissic granite has an Early Paleozoic crystallization age of 520.6 ± 2.8 Ma. This study, together with previous data, indicates that the massifs of northeastern China, including Erguna, Xing'an, Songliao, Jiamusi, and Khanka massifs, belonged to an orogenic belt that existed along the southern margin of the Siberian Craton during the late Pan-African period. The significant continental movements of this orogeny resulted in widespread magmatic activity in northeastern China from 530 Ma to 470 Ma under a tectonic setting that transitioned from compressional syn-collision to extensional postcollision. | HAO Yujie REN Yunsheng ZHAO Hualei LAI Ke ZHAO Xuan MA Yupeng | 2018 | Acta Geologica Sinica(English Edition)2018，92，1： | 4 |
| 20 | Infrared Spectroscopy Study of Structural Nature of Geopolymeric Products显示文摘The bonding status and chemical environment of SiO 4 and AlO 4 tetrahedras of three types of geopolymeric products were systematically investigated by infrared spectroscopy.The relationship between amorphous geopolymeric products and zeolite crystals with the same overall chemical compositions was also discussed.The infrared evidence shows that SiO 4 tetrahedra is partially bonded by AlO 4 during the hydration process of geopolymeric cement.The two types of tetrahedras jointly construct the three dimensional framework structures of the geopolymeric products.The mutual transformation between geopolymeric products and corresponding zeolite crystals will take place once the reaction condition is suitable,which reveals that the nature of geopolymeric products are probably the amorphous equivalent of the corresponding zeolite crystals. | ZHANG Yunsheng SUN Wei LI Zongjin | 2008 | Journal of Wuhan University of Technology(Materials Science)2008，23，4： | 4 |
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