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Column leaching of lanthanides from Abu Tartur phosphate ore with kinetic study

查看全文 作  者:A.T. [1]Kandil;M.M. [2]Aly;E.M. [2]Moussa;A.M. [1]Kamel;M.M. [2]Gouda;M.N. [2]Kouraim 高影响力作者 机构地区:[1]Chemistry Department, Faculty of Science, Helwan University;[2]Nuclear Materials Authority, P.O. Box 530, El Maadi, Cairo, Egypt高影响力机构 出  处:《Journal of Rare Earths》索引2010年第28卷第4期,共5页高影响力期刊 摘  要:The dynamic leaching of lanthanides from a west desert phosphate ore, Egypt (Abu Tartur) by hydrochloric acid, nitric acid and sulfuric acid solutions was investigated in this study as a function of acid concentration, flow rate and the presence of some additives such as boric acid. Also the kinetics of leaching of lanthanides was investigated as a function of temperature. It was found that the leaching process could be described by a shrinking-core model, with activation energy about 5.9, 13.8 and 21.9 kJ/M for leaching by HCl, HNO3 and H2SO4, respectively. Based on the experimental results, an empirical equation related to the rate constant of lanthanides leaching to leaching temperature was established for the purpose of process design. 关 键 词:沥滤的列 LANTHANIDES Abu Tartur 盐酸酸 硝酸 硫磺的酸 动力学 稀土元素
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