A new cryptand/paraquat [2]pseudorotaxane

查看全文 作　　者：ZAKHAROV Lev [1]N.;SLEBODNICK [2]Carla;RHEINGOLD Arnold [1]L.;GIBSON Harry [2]W.

机构地区：[1]Department of Chemistry and Biochemistry,University of California;[2]Department of Chemistry,Virginia Polytechnic Institute and State University

出　　处：《Science China Chemistry》索引2010年第53卷第4期,共5页

基　　金：supported by the National Science Foundation of USA (Grant No. DMR0097126);the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20070335152) 摘　　要：A new cryptand/paraquat [2]pseudorotaxane and its crown ether analog were synthesized and characterized by proton NMR, mass spectrometry, and single crystal X-ray analysis. The Job plots based on proton NMR data demonstrated that both the complex between cryptand 1 and paraquat derivative 2a and the complex between bis(p-phenylene)-34-crown-10 (3) and paraquat derivative 2b have 1:1 stoichiometry in solution. The apparent association constants (Ka,exp) of 1·2a and 3·2b calculated for 1:1 complexes were 1.4 (±0.2) × 104 and 4.7 (± 0.5) × 102 M-1, respectively. X-ray analysis showed that 1·2a is stabilized by ten hydrogen bonds and face-to-face π-stacking interactions in the solid state, while 3·2b is stabilized by four hydrogen bonds and face-to-face π-stacking interactions. As well as in the X-ray structure of 1·2c, a water molecule acts as a hydrogen bridge between the β-pyridinium protons of 2a and the ether oxygen atoms of 1 in 1·2a. The successful preparation of 1·2a demonstrated that the tert-butyl group is not big enough to be a stopper for rotaxanes based on 1. 关键词：HOST-GUEST system SELF-ASSEMBLY PSEUDOROTAXANE CRYPTAND PARAQUAT

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A new cryptand/paraquat [2]pseudorotaxane

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