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Thermodynamic Analysis and Experimental Investigation into Nonflame Combustion Technology(NFCT) with Thermal Cyclic Carrier

查看全文 作　　者：HEFang WANGHua DAIYong-[1]nian 高影响力作者 机构地区：[1]FacultyofMaterialsandMetallurgicalEngineering,KunmingUniversityofScienceandTechnology,Kunming650093,P.R.China高影响力机构 出　　处：《Chemical Research in Chinese Universities》索引2004年第20卷第5期,共5页高影响力期刊 基　　金：Supported by the National Natural Science Foundation of China(No.5 0 16 4 0 0 2 ) and Science & Technology Foundationof Baoshan Iron and Steel Co.L td 摘　　要：The utilization of fossil fuels causes serious negative impacts on the environment and human life. To mitigate greenhouse gases and other pollutants, a novel combustion process-the nonflame combustion technology with a thermal cyclic carrier of molten salt is introduced. In this technology, a whole combustion is divided into two steps, i.e., the section of producing oxide and the section of combustion. In the first step, oxygen is separated from air, and pure N2 is simultaneously formed which is easily recovered. In the other step, the fuels react with lattice oxygen in the oxides formed in the first step, and at the same time, thermal energy, CO2 and H2O vapor are produced. It is noted that the CO2 is easily separated from water vapor and ultimately captured. Theoretically, there are no environmental-unfriendly gases such as CO2, NOx and SO2 discharged in the whole combustion process. Some metal oxides scattered into molten salts play the roles of oxygen carriers in the combustion system, and they can constantly charge and discharge oxygen element from air to fuels during the combustion process. A nonflame combustion system with Li2CO3+K2CO3+Na2SO4 as the molten salt system, CH4 as the fuel and CuO as the catalyst was experimentally investigated. The experimental results show that the combustion process proceeded as it was theoretically analyzed, and CO2 with a high volume fraction of 77.0%95.0% and N2 with a high volume fraction of 91.9%99.3% were obtained. The high concentration of CO2 is favorable for capturing and storing subsequently. Therefore, the potential of reducing CO2 emissions of this nonflame combustion technology is huge. 关 键 词：热力学分析 无焰燃烧技术 熔盐 温室气体 热循环载体
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