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Preparation and Characterization of Polyaniline Nanofibers by Template-free Method

查看全文 作  者:Xuemei GUO, Kun LUO and Nanlin SHI Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China 高影响力作者 出  处:《Journal of Materials Science & Technology》索引2005年第21卷第2期,共4页高影响力期刊 摘  要:In the presence of p-toluene sulfonic acid (TSA) as a dopant, polyaniline (PAni) nanofibers, (about 80~165 nm in diameter) were successfully synthesized with a chemical template-free method. It was found that the formation probability, morphology, and diameter of the resulting PAni-TSA nanofibers were sensitive to the synthetic conditions,such as reaction temperature, the molar ratio of TSA to aniline, and the concentration of TSA in the polymerization media. The molecular structure was characterized by using the FT-IR, Raman spectra and X-ray diffraction, which shows that the main chain structure of PAni-TSA nanofibers was in agreement with that of granular PAni. 关 键 词:聚乙烯苯胺 纳米纤维 自由模版 TSA
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