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Synthesis and Characterization of Benzimidazolium Salts as Novel Ionic Liquids and their Catalytic Behavior in the Reaction of Alkylation

查看全文 作  者:WeiGuoHUANG BoCHEN YuanYuanWANG LiYiDAI [1]YongKuiSHAN 高影响力作者 机构地区:[1]CenterfortheChemistryofIonicLiquids,EastChinaNormalUniversity,Shanghai200062高影响力机构 出  处:《Chinese Chemical Letters》索引2005年第16卷第7期,共4页高影响力期刊 摘  要:A new series of ionic liquids have been prepared containing benzimidazolium cation (abbreviated as Bim). These salts were characterized by DSC, NMR, elemental analysis and thermogravimetric analysis. They showed different properties compared to imidazolium cation due to the introduction of benzene ring. The alkylation of benzene/diphenyl ether with 1-dodecene was carried in C4eBimBr-AlCl3 ionic liquids showing high catalytic activity when the mole ratio of C4eBimB:AlCl3 was 1:2. 关 键 词:离子液体 合成 晶体结构 烷基化反应 苯并咪唑阳离子 晶体行为学
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