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A Novel Cu-Mo/ZSM-5 Catalyst for NO_x Catalytic Reduction with Ammonia

查看全文 作  者:ZheLi DangLi WeiHuang [1]KechangXie 高影响力作者 机构地区:[1]KeyLaboratoryofCoalScienceandTechnologyofMinistryofEducationandShanxiProvince,CollegeofChemistryandChemicalEngineering,TaiyuanUniversityofTechnology,030024Taiyuan,China高影响力机构 出  处:《Journal of Natural Gas Chemistry》索引2005年第14卷第2期,共4页高影响力期刊 摘  要:The Cu-Mo/ZSM-5 catalysts with different Cu/Mo ratios were prepared by wet impregnation method, and their catalytic performance for selective catalytic reduction of NOx was studied. The results showed that Cu-Mo/ZSM-5 is a very effective catalyst for NOx catalytic reduction with ammonia, especially when Cu/Mo molar ratio is about 1.5. It not only exhibited the extremely high catalytic activity, but also showed good stability for O2. The bulk phase structure of Cu-Mo/ZSM-5 catalysts was determined by XRD technique, and the results indicated that there is a maximum dispersion for Cu species when Cu/Mo molar ratio is 1.5, and an interaction between Cu and Mo along with HZSM-5 may be present in Cu-Mo/ZSM-5, which may possibly result in a special structure favorable for the catalytic reduction of NOx over Cu-Mo/ZSM-5 catalyst. 关 键 词:铜-钼/ZSM-5催化剂 氨水 氮氧化物 选择性催化还原反应
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