A novel approach for one-step forming ε-caprolactam from cyclohexane nitrozation catalyzed by transition metal salt

查看全文 作　　者：Li Qiu [1,2]Mao;Bo Hua [2]Wu;Du Lin [2]Yin;Kui Yi [1]You;Ping Le [1]Liu;He An [1]Luo

机构地区：[1]College of Chemical Engineering, Xiangtan University, Xiangtan 411105, China;[2]Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081, China

出　　处：《Chinese Chemical Letters》索引2007年第18卷第3期,共3页

基　　金：The authors thank the financial support for this work by the National Natural Science Foundation of China(No.20233040). 摘　　要：The nitrozation reaction of cyclohexane in one-step reaction to form ε-caprolactam has been studied using transition metal salt as catalysts in this work. The results indicated that the catalysts play an especially important role. This method is expected to be a novel way to synthesize other lactam by similar reaction. The possible mechanism was suggested. 关键词：环己烷硝基化反应过渡金属盐催化 Ε-己内酰胺一步合成法

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A novel approach for one-step forming ε-caprolactam from cyclohexane nitrozation catalyzed by transition metal salt

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