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A potential approach to replace sulfurized olefins with borate ester containing xanthate group in lubricating oil

查看全文 作  者:WANG [1]YongGang;LI [2]JiuSheng;REN [1]TianHui 高影响力作者 机构地区:[1]School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China;[2]PetroChina Lanzhou Lubricating Oil R&D Institute, Lanzhou 730060, China高影响力机构 出  处:《Chinese Science Bulletin》索引2008年第53卷第7期,共6页高影响力期刊 基  金:the National 973 Basic Research Program of China (Grant No. 2007CB607606) 摘  要:To develop a potential substitute for sulfurized olefins, a borate ester derivative containing xanthate group (titled BXT) was synthesized and characterized. Meanwhile, its tribological properties in rape-seed oil were evaluated using four-ball tribometer. The results indicate that BXT shows excellent tri-bological capacity such as load-carrying, friction-reducing and antiwear property. Moreover, the syn-thesized compound has no noticeable odor, shows little corrosion to copper, and exhibits better ther-mal stability compared with sulfurized olefins. In order to study the action mechanism of BXT in friction process, analysis of the worn surface was carried out using a three-dimensional non-contact surface profilometer and XPS analyzer. 关 键 词:势能 硫化作用 烯烃 硼酸盐 黄原酸盐
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