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Biosorption of Cu^(2+) and Zn^(2+) by raw and autoclaved Rocella phycopsis

查看全文 作  者:Emine Yalc[1]ln;Kltigin [1]avusoglu;Kadir [1]Klnalloglu 高影响力作者 机构地区:[1]Department of Biology, Faculty of Science and Art, University of Giresun, 28049 Debboy Location, Giresun-Turkey高影响力机构 出  处:《Journal of Environmental Sciences》索引2010年第22卷第3期,共7页高影响力期刊 摘  要:The behavior of Cu2+ and Zn2+ biosorption onto raw and modified Roccella phycopsis from aqueous solutions was studied. Modification process was applied by autoclavation at 121°C for 30 min. The effcts of pH, initial metal concentration and biosorbent dosage were investigated. The maximum Cu2+ biosorption was achieved at pH 5.0 and the maximum biosorption capacities of 31.5 and 37.8 mg/g were recorded for raw and modified biosorbent, respectively. In the case of Zn2+ biosorption, maximum biosorption capacities were obtained at pH 4.0 as 29.1 and 35.3 mg/g for raw and modified biosorbent, respectively. Biosorption of Zn2+ and Cu2+ on all form of R. phycopsis increased much quickly with increasing initial metal concentrations from 10 to 100 mg/L. After modification process, probable changes in the surface polarity of raw and modified R. phycopsis were investigated by contact angle measurements. As expected, R. phycopsis has a polar surface and shows a highest contact angle with water, while after autoclavation water contact angle of R. phycopsis was significantly decreased from 47.5° to 34.4°. 关 键 词:生物吸附剂 锌吸附 原料 接触角测量 蒸压 表面极性 改造过程
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