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Microwave assisted atmospheric acid leaching of nickel from laterite ore

查看全文 作  者:CHE [1,2]Xiaokui;SU [3]Xiuzhu;CHI Ru'[3]an;YU [3]Junxia 高影响力作者 机构地区:[1]College of Resources and Civil Engineering, Northeastern University, Shenyang 110004, China;[2]Division of Mineral Resources, Metallurgy & Materials, General Research Institute for Nonferrous Metals, Beijing 100088, China;[3]Key Laboratory for Green Chemical Process of the Ministry of Education of China & Hubei Key Lab of Novel Reactor & Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430073, China高影响力机构 出  处:《Rare Metals》索引2010年第29卷第3期,共6页高影响力期刊 摘  要:The recovery of nickel from laterite ore with sulphuric acid under the effect of microwave irradiation was studied.The experimental results indicated that the extraction rate of nickel was influenced by reaction time,sulphuric acid concentration,and temperature,especially by microwave power.The results obtained from the experiments of orthogonal arrays showed that the optimum conditions of sulphuric acid concentration,reaction time,microwave power,and temperature were 25 vol.%,1.5 h,600 W,and 90°C,respectively.Under the optimal conditions,the nickel recovery could reach approximately 90.8%,which was higher than that obtained by conventional water bath heating.Kinetic experiments showed that the leaching of nickel in a sulphuric acid medium was controlled by chemical reaction occurring on the surface of laterite ore.The apparent activation energy was 38.9 kJ/mol.Microwave heating technology is efficient,clean,and easy to control and facilitate continuous processing of materials. 关 键 词:镍红土矿 微波辅助 常压酸浸 硫酸浓度 反应时间 最佳条件 表观活化能 微波辐射
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