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Dispersion polymerization of anionic polyacrylamide in an aqueous salt medium

查看全文 作  者:Lu Jiao Peng Bo Li Mingyuan Lin Meiqin Dong [1]Zhaoxia 高影响力作者 机构地区:[1]Enhanced Oil Recovery Research Center, China University of Petroleum, Beijing 102249, China高影响力机构 出  处:《Petroleum Science》索引2010年第7卷第3期,共6页高影响力期刊 摘  要:Anionic polyacrylamide dispersions were prepared by dispersion polymerization in an aqueous salt medium, using acrylamide(AM) and acrylic acid(AA) as monomers and anionic polyelectrolytes as stabilizer. Effects of salt concentration, and molecular weight and concentration of stabilizers on the stability of the dispersions were investigated using a HAAKE rheometer and optical microscopy. The results showed that stable anionic polyacrylamide dispersions, consisting of smooth, spherical, polydisperse particles, could be obtained under the conditions of salt concentration ranging from 26 wt% to 30 wt%, concentration of stabilizers from 1.2 wt% to 1.8 wt%, and intrinsic viscosity of stabilizers from 2.98 dL·g-1 to 3.74 dL·g-1 . The apparent viscosity of the stable dispersions changed very little with the shear rate, showing Newton fluid behavior. 关 键 词:阴离子聚丙烯酰胺 盐水溶液 分散聚合 HAAKE流变仪 阴离子聚电解质 聚丙烯酰胺乳液 质量分数 稳定剂
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