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Assessment of mercury(II) bioavailability using a bioluminescent bacterial biosensor: Practical and theoretical challenges

查看全文 作  者:Paulo R G [1]Barrocas;William M [2]Landing;Robert J M [3]Hudson 高影响力作者 机构地区:[1]Department of Sanitation and Environmental Health, National School of Public Health, Oswaldo Cruz Foundation;[2]Department of Oceanography, Florida State University. Tallahassee;[3]Department of Natural Resources and Environmental Sciences, University of Illinois高影响力机构 出  处:《Journal of Environmental Sciences》索引2010年第22卷第8期,共7页高影响力期刊 基  金:funded by Florida Department of Environmental Protection (contract SP507) 摘  要:Critical methodological challenges in the microbial biosensor approach to assessing Hg(II) bioavailability were evaluated from the perspective of analytical chemists. The main challenge stems from the fact that the chemical speciation of Hg(II) in natural waters exerts a major control on its bioavailability, yet its natural complexation equilibria are extensively altered during conventional bioassays. New data, obtained using a bioluminescent Hg(II)-biosensor, that illustrate these challenges are presented and potential solutions proposed. 关 键 词:生物发光细菌 生物传感器 生物利用度 汞(Ⅱ) 评估 自然水域 微生物方法 分析化学家
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