Two new compounds with microporous constructed by Waugh-type polyoxoanion and transition metal ions

查看全文 作　　者：TAN [1]HuaQiao;CHEN [1]WeiLin;LIU [1]Ding;YAN [1]AiXue;WANG [1]EnBo

机构地区：[1]Key Laboratory of Polyoxometalate Science of Ministry of Education,Northeast Normal University,Changchun 130024,China

出　　处：《Science China Chemistry》索引2011年第54卷第9期,共5页

基　　金：financially supported by the National Natural Science Foundation of China(20701005 & 20701006);the Fundamental Research Funds for the Central Universitues,Postdoctoral Station Foundation of Ministry of Education(20060200002);the Testing Foundation of Northeast Normal University(NENU),Science and Technology Creation Foundation of NENU(NENU-STC07009);the Program for Changjiang Scholars and Innovative Research Team in University 摘　　要：Two new compounds with microporous Co3[MnMo9O32].15H2O(1) and Cu3[MnMo9O32].15H2O(2) have been synthesized,and characterized by IR,element analysis,TG and single-crystal X-ray analysis.The structure analyses reveal that compounds 1 and 2 are isostructural.In crystal,the Waugh-type polyoxoanions [MnMo9O32]6-are connected by Co2+ or Cu2+ cations to a 3D open-framework,which possesses channels along the [1 2 2] direction of approximately 8.27 × 11.97 .The photocatalytic performances of compounds 1 and 2 for photodegradation of RhB with UV irradiation have been studied,which show a good photocatalytic activity for photodegradation of RhB. 关键词：新化合物过渡金属离子孔构造射线衍射分析光催化性能紫外线照射光催化活性红外光谱

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Two new compounds with microporous constructed by Waugh-type polyoxoanion and transition metal ions

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