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Revisiting Al-Ni-Zr bulk metallic glasses using the 'cluster-resonance' model

查看全文 作  者:LI FengWei QIANG JianBing WANG YingMin WANG Qing DONG XingLong DONG [1]Chuang 高影响力作者 机构地区:[1]Key Laboratory of Materials Modification of Ministry of Education, Dalian University of Technology, Dalian 116024, China高影响力机构 出  处:《Chinese Science Bulletin》索引2011年第56卷第36期,共6页高影响力期刊 基  金:supported by the National Natural Science Foundation of China (51041011 and 50901012);the National Basic Research Priorities Program of China (2007CB613902) 摘  要:Six series of alloys,namely,Ni3Zr6Alx,Ni3Zr7Alx,Ni4Zr9Alx,Ni3Zr8Alx,Ni3Zr9Alx and Ni3Zr10Alx (x=1,1.5,2,3) were designed in this work and the bulk metallic glass (BMG) formation of these compositions was investigated by copper mold suction casting. A centimeter-scale BMG sample was obtained for the Ni4Zr9Al2 (Al13.3Ni26.7Zr60 in atomic percent) composition. The thermal glass parameters for this BMG were determined to be ΔTx = 68 K,Trg = 0.579,and γm = 0.689. Using the 'cluster-resonance' model for glass formation an optimal BMG composition was determined using the cluster formula [Ni3Zr9](Al2Ni1). 关 键 词:大块金属玻璃 共振 集群 BMG 玻璃形成
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