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Size distribution and chemical composition of secondary organic aerosol formed from Cl-initiated oxidation of toluene

查看全文 作  者:Mingqiang [1,2,3]Huang;Weijun [1,2]Zhang;Xuejun [1,2]Gu;Changjin [1,2]Hu;Weixiong [1,2]Zhao;Zhenya [1,2]Wang;Li [1,2]Fang 高影响力作者 机构地区:[1]Key Laboratory of Atmospheric Composition and Optical Radiation,Anhui Institute of Optics&Fine Mechanics,Chinese Academy of Sciences,Hefei 230031,China;[2]Laboratory of Environment Spectroscopy,Anhui Institute of Optics&Fine Mechanics,Chinese Academy of Sciences,Hefei 230031,China;[3]Department of Environmental Science and Engineering,Xiamen University,Tan Kah Kee College,Zhangzhou 363105,China高影响力机构 出  处:《Journal of Environmental Sciences》索引2012年第24卷第5期,共5页高影响力期刊 基  金:supported by the Open Research Fund of Key Laboratory of Atmospheric Composition and Optical Radiation, Chinese Academy of Sciences (No. JJ-10-04);the National Natural Science Foundation of China (No.40975080, 10979061);class A technology fund of Department of Education of Fujian Province (No. JA11290) 摘  要:Secondary organic aerosol (SOA) formed from Cl-initiated oxidation of toluene was investigated in a home-made smog chamber. The size distribution and chemical composition of SOA particles were measured using aerodynamic particle sizer spectrometer and the aerosol laser time-of-flight mass spectrometer (ALTOFMS), respectively. According to a large number of single aerosol diameter and mass spectra, the size distribution and chemical composition of SOA were obtained statistically. Experimental results showed that SOA particles created by Cl-initiated oxidation of toluene is predominantly in the form of fine particles, which have diameters less than 2.5 μm (i.e., PM2.5), and glyoxal, benzaldehyde, benzyl alcohol, benzoquinone, benzoic acid, benzyl hydroperoxide and benzyl methyl nitrate are the major products components in the SOA. The possible reaction mechanisms leading to these products are also proposed. 关 键 词:二次有机气溶胶 颗粒粒度分布 化学组成 氧化氯 氯甲苯 SOA 空气动力学 化学成分
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