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Enhancement of CO_2 adsorption on nanoporous chromium terephthalate(MIL-101) by amine modification

查看全文 作  者:Mansoor [1]Anbia;Vahid [1]Hoseini 高影响力作者 机构地区:[1]Research Laboratory of Nanoporous Materials,Faculty of Chemistry,Iran University of Science and Technology,Farjam Street,Narmak,Tehran 16846,Iran高影响力机构 出  处:《Journal of Natural Gas Chemistry》索引2012年第21卷第3期,共5页高影响力期刊 摘  要:Carbon dioxide(CO 2) adsorption on a standard metal-organic framework MIL-101 and a pentaethylenehexamine modified MIL-101(PEHAMIL-101) are investigated and compared in this study.The adsorbent samples were characterized by XRD,FT-IR and nitrogen adsorptiondesorption isotherms analysis.CO 2 adsorption capacity was measured by a volumetric method.MIL-101 and PEHA-MIL-101 exhibited CO 2 adsorption capacities of 0.85 and 1.3 mmol CO 2 /g adsorbent at 10 bar and 298 K,respectively.It is observed that CO 2 adsorption capacity was fairly improved about 50% after amine modification. 关 键 词:对苯二甲酸乙二醇酯 二氧化碳 胺修饰 碳吸附 多孔 吸附能力 FT-IR 金属有机
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