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Separation of Salbutamol by Nano-baskets of Calix[4]arene Bearing Sulfonyl-carboxamides in Partial-cone Conformation

查看全文 作  者:MOKHTARI [1]Bahram;POURABDOLLAH [1]Kobra 高影响力作者 机构地区:[1]Razi Chemistry Research Center(RCRC),Shahreza Branch,Islamic Azad University高影响力机构 出  处:《Chemical Research in Chinese Universities》索引2012年第28卷第6期,共7页高影响力期刊 基  金:Supported by the Project of Islamic Azad University(Shahreza Branch);the Iran Nanotechnology Initiative Council 摘  要:Salbutamol,which increases the muscle mass and decreases the adipose tissue,is misused as nutrient repartitioning agent in the livestock.The novelty of this work is the determination of salbutamol in the livestock meat via new bonded-phases bearing eight derivatives of p-tert-calix[4]arene in partial-cone conformation.The new synthesized bonded-phases were characterized and optimized.The bonding interactions of solute and stationary-phases were examined and the main interactions were reported.The salbutamol levels in six samples of livestock meat were analyzed and the results reveal that for the best bonded-phases,the limit of detection(LOD) and limit of quantitation(LOQ) were 0.02 and 0.06 μg/mL,respectively. 关 键 词:杯[4]芳烃衍生物 沙丁胺醇 构象 锥式 轴承 甲酰胺 磺酰基 氢键相互作用
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