Linker extension through hard-soft selective metal coordination for the construction of a non-rigid metal-organic framework

查看全文 作　　者：WEI [1]ZhangWen;YUAN [2]DaQiang;ZHAO [3]XiaoLiang;SUN [3]DaoFeng;ZHOU Hong-[1]Cai

机构地区：[1]Department of Chemistry, Texas A&M University, College Station;[2]Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences;[3]Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University

出　　处：《Science China Chemistry》索引2013年第56卷第4期,共5页

基　　金：supported by the U.S. Department of Energy (DOE Grants DE-FC36-07GO17033);the Welch Foundation (A-1725);supported by the National Science Foundation/Department of Energy under grant number NSF/CHE-0822838;supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357 摘　　要：A metal-organic framework (MOF) has been obtained by using a linker extension strategy. Three di-anions of 4-(3,5-dimethyl- 1H-pyrazol-4-yl)-benzoic acid coordinate to three Cu(Ⅰ) ions forming an extended trigonal planar ligand, which links three di-copper paddlewheel units giving rise to a Pt3O4 net. 关键词：连接器金属非刚性骨架铜(I) 平面三角形阴离子 MOF

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Linker extension through hard-soft selective metal coordination for the construction of a non-rigid metal-organic framework

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