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Thermodynamic analysis and formula optimization of steel slag-based ceramic materials by FACTsage software

查看全文 作  者:Xian-bin [1,2]Ai;Hao [1,2]Bai;Li-hua [1,2]Zhao;Da-qiang [1,2]Cang;Qi [3]Tang 高影响力作者 机构地区:[1]State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing;[2]School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing;[3]Foshan Oceano Ceramic Co., Ltd.高影响力机构 出  处:《International Journal of Minerals,Metallurgy and Materials》索引2013年第20卷第4期,共7页高影响力期刊 基  金:financially supported by the National Natural Science Foundation of China (Nos. 51034008 and 51004012);the National High Technology Research and Development Program of China (No. 2011AA06A105) 摘  要:Using steel slag as a main raw material of ceramics is considered as a high value-added way. However, the relationship among the initial composition, ceramic microstructure, and macroscopic properties requires further study. In this paper, a series of ceramics with different slag ratios (0-70wt%) were designed, and the software FACTsage was introduced to simulate the formation of crystalline phases. The simulation results indicate that mullite is generated but drastically reduced at the slag ratios of 0-25wt%, and anorthite is the dominant crystalline phase in the slag content of 25wt%-45wt%. When the slag ratio is above 45wt%, pyroxene is generated more than anorthite. This is because increasing magnesium can promote the formation of pyroxene. Then, the formula with a slag content of 40wt% was selected and optimized. X-ray diffraction results were good consistent with the simulation results. Finally, the water absorption and bending strength of optimized samples were measured. 关 键 词:陶瓷材料 配方优化 热力学分析 软件 钢渣 X-射线衍射 重量比 高附加值
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