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Enhancing the power conversion efficiency of PCDTBT:PC_(71)BM polymer solar cells using a mixture of solvents

查看全文 作  者:Shaopeng [1]Yang;Ye [1]Zhang;Tao [1]Jiang;Xuefeng [1]Sun;Chaoqun [1]Lu;Guang [1]Li;Xiaowei [1]Li;Guangsheng [1]Fu 高影响力作者 机构地区:[1]Hebei Key Laboratory of Optic-electronic Information Materials,College of Physics Science and Technology,Hebei University高影响力机构 出  处:《Chinese Science Bulletin》索引2014年第59卷第3期,共4页高影响力期刊 基  金:supported by the Natural Science Foundation of Hebei Province(F2010000306,F2012201089);the Hebei Province Department of Education Fund(ZH2011205) 摘  要:Organic polymer solar materials are shown to exhibit better solubility in mixed solvents than in pure ones,which affects the performance of their solar cells.In this article,poly[N-9-hepta-decanyl-2,7-carbazole-alt-5,5-(4.7-di-2-thienyI-2,l,3-benzothiadiazole)(PCDTBT0)and[6,6]-phenyl-C71-butyric acid methyl ester(PC_(71)BM)are used as active layer materials in solar cells.To optimize the performance of these active materials,the ratio of chloroform(CF)to chlorobenzene used as solvents to dissolve PCDTBT,and PC_(71)BM is varied,which is shown to affect power conversion efficiency(PCE).The solar cell that shows the best performance with a PCE as high as 6.82%is produced using a volume ratio of CF to chlorobenzene of1:1. 关 键 词:太阳能电池材料 有机聚合物 电源转换效率 溶剂比 混合物 功率转换效率 最佳性能 苯并噻二唑
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