Comparison of Phosphorus Sorption by Light-Weight Aggregates Produced in the United States

查看全文 作　　者：[1,2]M.D.BAKER;[1]S.SIMKINS;[1]L.A.SPOKAS;[1]P.L.M.VENEMAN;[1]B.S.XING

机构地区：[1]Stockbridge School of Agriculture,University of Massachusetts,Amherst,MA 01003 (USA);[2]U.S.Army,Fort Hood,TX 76544 (USA)

出　　处：《Pedosphere》索引2014年第24卷第6期,共9页

基　　金：Supported by the Soil Characterization Laboratory,University of Masachusetts,Amherst,MA,USA 摘　　要：In this study, phosphorus(P) sorption of thirteen light-weight aggregates(LWAs) from USA was compared during batch equilibrium experiments in order to identify those materials which had the highest P sorption capacity for further study. Seven different levels of sorption activity were observed, which were broadly grouped into three categories—high performing, middle performing, and low performing aggregates. Chemical analysis of Ca, Al, Fe, and Mg was used to describe the differences between LWAs. There was a significant correlation between cation(especially Al, Ca, Fe, and Mg) content and P sorbed. Langmuir isotherms were used to describe P sorption maximum and binding affinity for four of the top five performing LWAs, Universal, Stalite 'D', Stalite 'Mix', and TXI.The fifth aggregate, Lehigh, exhibited more complex sorption, and was better described by the Freundlich isotherm. Universal had a mean P sorption at the highest concentration of 824 mg kg-1, well above its calculated sorption maximum(702 mg kg-1), and also had the highest binding affinity(1.1 L mg-1). This experiment suggests that the top performing LWA(Universal) may perform poorly in column and field studies due to observed precipitates, which could degrade constructed wetland performance. Other LWAs may exhibit superior field performance due to their high calculated sorption maxima. In general, these results highlight the importance of batch experiments as a first step in identifying materials suitable for column and field experiments. 关键词：磷吸附美国料比实验比较试验材料吸附能力吸附活性化学分析

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Comparison of Phosphorus Sorption by Light-Weight Aggregates Produced in the United States

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