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Visible Light Photocatalytic Properties and Thermochromic Phenomena of Nanostructured BiOCl Microspheres

查看全文 作  者:Jiushan [1]Cheng;Cong [1]Wang;Yinfang [1]Cui;Ying [1]Sun;Ying [1]Zuo 高影响力作者 机构地区:[1]Center for Condensed Matter and Material Physics,Department of Physics,Beihang University高影响力机构 出  处:《Journal of Materials Science & Technology》索引2014年第30卷第11期,共4页高影响力期刊 基  金:supported by the National Natural Science Foundation of China (NSFC) (No.51172012) 摘  要:Black nanostructured Bi OCl microspheres were directly synthesized by a hydrothermal method. The black balllike Bi OCl microspheres and black flower-like Bi OCl microspheres were obtained using different surfactant.The color of the Bi OCl microspheres turned from black to white when being annealed at 400℃ in air for 3 h and could be recovered to black by exposure to ultraviolet light for a few hours. The photocatalytic activity of both the black and the white Bi OCl microspheres was characterized by the photo-degradation of methyl orange dye under visible light irradiation. The black ball-like nanostructure Bi OCl displayed the best photocatalytic activity, compared with the white Bi OCl and the black flower-like Bi OCl. It can degrade the methyl orange dye to 20% within 70 min under visible light irradiation. The high activity of the Bi OCl ball-like sphere may own to its special morphology, strong absorption in visible light range and the existence of oxygen vacancies. 关 键 词:可见光照射 纳米结构 光催化性能 微球 热致变色 光催化活性 水热法合成 表面活性剂
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