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Multi-walled carbon nanotubes as novel promoter of catalysts for certain hydrogenation and dehydrogenation reactions

查看全文 作  者:Guodong [1,2,3]Lin;Xuelian [1,2,3]Liang;Zhiming [1,2,3]Liu;Jianrong [1,2,3]Xie;Binghui [1,2,3]Chen;Hongbin [1,2,3]Zhang 高影响力作者 机构地区:[1]State Key Laboratory of Physical Chemistry of Solid Surfaces;[2]National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters;[3]College of Chemistry and Chemical Engineering, Xiamen University高影响力机构 出  处:《Science China Chemistry》索引2015年第58卷第1期,共13页高影响力期刊 基  金:supported by the National Basic Research Program of China(2011CBA00508);the National Natural Science Foundation of China(20923004);the Program for Changjiang Scholars and Innovative Research Team in University(IRT1036) 摘  要:From the chemical catalysis viewpoint,the excellent performance of CNTs in adsorption-activation of H2 and in promoting spillover of adsorbed H-species is very attractive,in addition to their nanosize channels,sp2-C constructed surfaces,and high thermal/electrical conductivity.This review examines some recent progresses of CNTs as a novel support or promoter of catalysts for certain hydrogenation or dehydrogenation reactions,e.g.,hydrogenation-conversion of syngas to yield alcohols and decomposition or steam-reforming of methanol to generate H2,mainly based on recent work carried out in our laboratory. 关 键 词:多壁碳纳米管 新型催化剂 脱氢反应 加氢 启动子 化学催化 纳米通道 蒸汽重整
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