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A Comparative Investigation on the Structural,Optical and Electrical Properties of SiO_2-Fe_3O_4 Core-Shell Nanostructures with Their Single Components

查看全文 作  者:Neena [1]Bachan;[2]A.Asha;W.Jothi [1]Jeyarani;D.Arun [3]Kumar;J.Merline [1]Shyla 高影响力作者 机构地区:[1]Department of Physics,Energy NanoTechnology Centre(ENTeC),Loyola Institute of Frontier Energy(LIFE),Loyola College;[2]Department of Physics,Dhanalakshmi Srinivasan College of Engineering and Technology;[3]Department of Physics,Shri Andal Alagar College of Engineering高影响力机构 出  处:《Acta Metallurgica Sinica(English Letters)》索引2015年第28卷第11期,共9页高影响力期刊 摘  要:The SiO_2-Fe_3O_4 core-shell nanostructures were synthesized by sol-gel chemistry.The morphological features of the nanostructures were examined by field emission scanning electron microscopy which revealed the core-shell nature of the nanoparticles.X-ray diffraction studies evidenced the formation of SiO_2-Fe_3O_4 core-shell nanostructures with high degree of homogeneity.The elemental composition of the SiO_2-Fe_3O_4 core-shell nanostructures was determined by energy-dispersive X-ray spectroscopy analysis.Fourier transform infrared spectroscopy showed the Si-O-Fe stretching vibrations.On analysis of the optical properties with UV-Vis spectra and Tauc's plot,it was found that the band gap of SiO_2-Fe_3O_4 core-shell nanostructures diminished to 1.5 eV.Investigation of the electrical properties of the core-shell nanostructures using field-dependent conductivity measurements presented a significant increase in photoconductivity as compared to those of its single components,thereby rendering them as promising candidates for application as photoelectrodes in dye-sensitized solar cells. 关 键 词:核壳结构 纳米结构 电学性质 光学特性 成分 电子显微镜观察 傅里叶变换红外光谱 染料敏化太阳能电池
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