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A Novel 3D Twofold Zn(Ⅱ) Coordination Polymer Constructed by Mixed Flexible Ligands:Synthesis,Crystal Structure and Fluorescence Property

查看全文 作  者:[1]李培煊;[1,2]卢久富 高影响力作者 机构地区:[1]School of Energy Science and Engineering,Xi’an University of Science and Technology;[2]Shaanxi Province Key Laboratory of Catalytic Foundation and Application,College of Chemical & Environment Science, Shaanxi Sci-Tech University高影响力机构 出  处:《Chinese Journal of Structural Chemistry》索引2017年第36卷第2期,共7页高影响力期刊 基  金:Supported by the National Youth Natural Science Foundation of China(No.21603133) 摘  要:A new Zn(Ⅱ) coordination polymer, {[Zn(1,3-bip)(oba)]·0.5H_2O}n(1),1,3-bip =1,3-bis(imidazole)propane, H_2oba=4,4?-oxybis(benzoate)), have been synthesized and characterized by single-crystal X-ray diffraction, powder XRD, FTIR, TGA and elemental analysis techniques. The single-crystal X-ray diffraction reveals that complex 1 shows a 3D→3D twofold interpenetrating network that can be described as a 4-connected uninodal net with(65.8) topology. In addition, the photoluminescence property of complex 1 was also investigated at room temperature. 关 键 词:锌配位聚合物 荧光性质 晶体结构 合成 单晶X-射线衍射 三维 配体 柔性
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