C(sp^3)–H bond functionalization of non-cyclic ethers by decarboxylative oxidative coupling with α,β-unsaturated carboxylic acids

查看全文 作　　者：Tong [1,2]Zhang;Xing-Wang [1,2]Lan;Yu-Qiang [1,2]Zhou;Nai-Xing [1,2]Wang;Yue-Hua [1,2]Wu;Yalan [3]Xing;Jia-Long [4]Wen

机构地区：[1]Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;[2]University of Chinese Academy of Sciences, Beifing 100049, China;[3]Department of Chemistry, William Paterson University of New Jersey, New Jersey 07470, United States;[4]Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, China

出　　处：《Science China Chemistry》索引2018年第61卷第2期,共4页

基　　金：supported by the National Natural Science Foundation of China (21572240) 摘　　要：A copper-catalyzed decarboxylative oxidative coupling of α,β-unsaturated carboxylic acids with non-cyclic ethers is developed.This method provides a new approach for C(sp^3)–H bond functionalization of non-cyclic ethers. Mechanism study shows the reaction involves a radical process. 关键词：不饱和周期氧化羧基醚催化铜

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C(sp^3)–H bond functionalization of non-cyclic ethers by decarboxylative oxidative coupling with α,β-unsaturated carboxylic acids

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