Understanding the structural evolution of Au/WO_(2.7) compounds in hydrogen atmosphere by atomic scale in situ environmental TEM

查看全文 作　　者：Fei [1]Hui;Chong [2]Li;Yanhui [1]Chen;Chunhui [1]Wang;Jingping [1]Huang;Ang [1]Li;Wei [1]Li;Jin [3]Zou;Xiaodong [1]Han

机构地区：[1]Key Lab of Microstructure and Property of Advanced Materials,Beijing University of Technology,Beijing,100124,China;[2]International Laboratory for Quantum Functional Materials of Henan,School of Physics and Microelectronics,Zhengzhou University,Zhengzhou,450001,China;[3]School of Mechanical and Mining Engineering and Centre for Microscopy and Microanalysis,The University of Queensland,St Lucia,QLD,4072,Australia

出　　处：《Nano Research》索引2020年第13卷第11期,共6页

基　　金：supported by grants from the National Natural Science Foundation of China(Nos.51988101,91860202 and 51872008);the Beijing Natural Science Foundation(No.Z180014);the“111”project under the DB18015 grant and the Beijing Outstanding Young Scientists Projects(No.BJJWZYJH01201910005018).The authors thank Dr.Dongchang Wu from Thermofisher Scientific Shanghai Nanoport for the useful discussion and assistance with Titan-ETEM and Titan-Themis. 摘　　要：Hydrogen energy is a resuscitated clean energy source and its sensitive detection in air is crucial due to its very low explosive limit.Metal oxide decorated with noble metal nanoparticles has been used for the enhancement of gas detection and exhibits superior sensitivity.Understanding the intrinsic mechanism of the detection and the enhancement mechanism is thus becoming a fundamental issue for the further development of novel metal/oxide compound gas-sensing materials.However,the correlation between the microstructural evolution,the charge transport and the complex sensing process has not yet been directly revealed and its atomic mechanism is still debatable.In this study,an Au/WO_(2.7) compound was synthesized and exhibited a strongly enhanced gas sensitivity to many reductive gases,especially H2.Aberration-corrected environmental transmission electron microscopy was used to investigate the atomic-scale microstructural evolution in situ during the reaction between H_(2) and Au/WO_(2.7) compound.Swing and sintering processes of the Au particles on the WO_(2.7) surface were observed under heating and gaseous environments,and no injection of hydrogen atoms was suggested.First principle calculations verified the swing and sintering processes,and they can be explained by the enhancement of H2 sensitivity. 关键词：in situ environmental TEM H2 sensing Au/WO_(2.7) gas-solid interface

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Understanding the structural evolution of Au/WO_(2.7) compounds in hydrogen atmosphere by atomic scale in situ environmental TEM

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