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Electrical properties of yttrium calcium oxyborate crystal annealed at high temperature and low oxygen partial pressure

查看全文 作　　者：Shiwei [1]Tian;Lili [1]Li;Feifei [1]Chen;Chao [1]Jiang;Fapeng [1]Yu;Yanlu [1]Li;Xiulan [1]Duan;Zhengping [1]Wang;Shujun [2]Zhang;Xian [1]Zhao 高影响力作者 机构地区：[1]State Key Laboratory of Crystal Materials,Advanced Research Center for Optics of Shandong University,Jinan,250100,China;[2]ISEM,Australia Institute of Innovative Materials,University of Wollongong,Wollongong,NSW,2500,Australia高影响力机构 出　　处：《Journal of Materiomics》索引2019年第5卷第3期,共9页高影响力期刊 基　　金：financially supported by the Primary Research&Development Plan of Shandong Province(2017CXGC0413);the National Natural Science Foundation of China(51872165). 摘　　要：The yttrium calcium oxyborate crystal(YCa_(4)O(BO_(3))_(3),YCOB)has been actively studied for hightemperature piezoelectric sensing applications.In this work,the stability of electric properties of YCOB crystal annealed in critical conditions(high-temperatures of 900-1100℃ with a low oxygen partial pressure of 4×10^(-6) atm for 24 h)was investigated and the recovery mechanism for the electrical resisitivity,dielectric permittivity and dielectric loss were studied,taking advantage of the X-ray photoelectron spectra and the first principle calculations.The electrical resistivity of the annealed YCOB crystal was slightly decreased when compared to the pristine counterpart,being(2-5)×10^(7) Ω·cm at 850C.The dielectric permittivity and dielectric loss were found to increase after annealing,showing recoverable behaviours after thermal treatment above 650℃ in air.The calculated vacancy formation energy indicates that the oxygen vacancy is the dominant defects in YCOB.The formation of oxygen vacancy weakens the chemical bonding strength between B(Ca or Y)and O atoms,introduces extra donor levels in the band gap,which excites the electrons to conduction band more easily thus enhances the electrical conductivity and dielectric loss.The recovered electrical properties are believed to be associated with the reduced vacancy defects at elevated temperatures in air. 关 键 词：YCOB crystal Recoverable dielectric properties First principle calculations
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