Recent progress in structural modulation of metal nanomaterials for electrocatalytic CO_(2) reduction

查看全文 作　　者：Chen-Huai [1]Yang;Farhat [2]Nosheen;Zhi-Cheng [1]Zhang

机构地区：[1]Tianjin Key Laboratory of Molecular Optoelectronic Sciences,Department of Chemistry,School of Science,Tianjin University&Collaborative Innovation Center of Chemical Science and Engineering,Tianjin 300072,China;[2]Department of Chemistry,Division of Science and Technology,University of Education,Lahore 54660,Pakistan

出　　处：《Rare Metals》索引2021年第40卷第6期,共19页

基　　金：financially supported by the National Key R&D Program(N os.2017 YF A0204503 and 2016YFB0401100);the National Natural Science Foundation of China(Nos.91833306,21875158,51633006 and 51703159)。 摘　　要：The electrochemical CO_(2) reduction(ECR)into value-added products presents an appealing approach to mitigate CO_(2) emission caused by excess consumption of fossil fuels.To obtain high catalytic activity and selectivity toward target product in ECR,designing and developing a stable and efficient electrocatalyst is of significant importance.To date,metal nanomaterials have been widely applied as electrocatalysts for ECR due to their unique physicochemical properties.The structural modulation of metal nanomaterials is an attractive strategy to improve the catalytic performance.In this review,the recent progress of structural modulation,including size,facet,grain boundary,composition,interface,ligand modification,and crystal phase,is systematically summarized from both theoretical and experimental aspects.Finally,the opportunities and perspectives of structural modulation of metal nanomaterials for ECR are proposed. 关键词：CO_(2)reduction Structural modulation ELECTROCATALYSIS Metal nanomaterial Crystal phase

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Recent progress in structural modulation of metal nanomaterials for electrocatalytic CO_(2) reduction

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