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Electron Paramagnetic Resonance and Optical Absorption of VO2+Doped Ammonium Selenate Single Crystals

查看全文 作  者:Ram [1]Kripal;Ashutosh Kumar [2]Shukla 高影响力作者 机构地区:[1]Department of Physics,University of Allahabad,Allahabad 211002,India;[2]Department of Physics,Ewing Christian College,Allahabad 211003,India高影响力机构 出  处:《Chinese Physics Letters》索引2011年第28卷第3期,共4页高影响力期刊 基  金:One of the authors(AKS)is supported by the Research Project of University Grants Commission,New Delhi. 摘  要:An electron paramagnetic resonance study of vanadyl ions doped in ammonium selenate single crystals is carried out at room temperature.It is found that the VO^(2+)ion takes up an interstitial site.The spin Hamiltonian parameters obtained from the crystal rotations are g‖=1.9576±0.0002,g⊥=1.9889±0.0002,A‖=203±2 G,A⊥=78±2 G.An optical absorption study is also carried out to evaluate various bonding parameters.On the basis of these parameters the nature of bonding in the complex is discussed. 关 键 词:temperature parameters BONDING
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