Alternating current electrolysis:A photoredox catalysis mimic and beyond

查看全文 作　　者：Junsong [1]Zhong;Chenglin [1]Ding;Hyunwoo [2]Kim;Terry [3]McCallum;Keyin [1,4]Ye

机构地区：[1]Institute of Pharmaceutical Science and Technology,College of Chemistry,Fuzhou University,Fuzhou 350108,China;[2]Department of Chemistry and Nanoscience,Ewha Womans University,Seoul 03760,South Korea;[3]The Canadian Bank Note Company,Ottawa,Ontario 91758,Canada;[4]State Key Laboratory of Physical Chemistry of Solid Surfaces,Xiamen University,Xiamen 361005,China

出　　处：《Green Synthesis and Catalysis》索引2022年第3卷第1期,共7页

基　　金：This work was supported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(No.NRF-2021R1C1C1004605)(H.Kim);the National Natural Science Foundation of China(Nos.22171046,21901041)(K.Y). 摘　　要：Alternating current electrolysis(ACE)is an emerging powerful synthetic tool,which principally resembles photoredox catalysis strategies.Its periodically alternating polarity feature allows oxidation and reduction processes to take place on the same electrode surface in a well-controlled manner via the fine-tuning of current frequency along with other reaction parameters.Therefore,many challenging transformations in typical direct electrolysis,including constant current electrolysis or constant potential electrolysis,could be achieved via ACE.The recent advances in the organic synthesis using this emerging technology and its advantages over direct electrolysis are highlighted. 关键词：ELECTROCHEMISTRY Photoredox catalysis Alternating current electrolysis Green chemistry SELECTIVITY

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Alternating current electrolysis:A photoredox catalysis mimic and beyond

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