Structural survey of metal-covalent organic frameworks and covalent metal-organic frameworks

查看全文 作　　者：Chaozhi [1]Xiong;Zhenwu [1]Shao;Jia’nan [2]Hong;Kexin [3]Bi;Qingsong [1]Huang;Chong [1]Liu

机构地区：[1]School of Chemical Engineering,Sichuan University,Chengdu 610065,China;[2]Beijing Changping Hospital of Integrated Chinese and Western Medicine,Beijing 102208,China;[3]Department of Bioprocess Engineering,Institute of Biotechnology,Technische Universitat Berlin,Berlin 10623,Germany

出　　处：《International Journal of Minerals,Metallurgy and Materials》索引2023年第30卷第12期,共13页

基　　金：financially supported by the National Natural Science Foundation of China(No.22176135);the Fundamental Research Funds for the Central Universities in China(No.YJ201976)。 摘　　要：This review offers an overview of the latest developments in metal-covalent organic framework(MCOF)and covalent metal-organic framework(CMOF)materials,whose construction entails a combination of reversible coordination and covalent bonding adapted from metal-organic frameworks(MOFs)and covalent organic frameworks(COFs),respectively.With an emphasis on the MCOF and CMOF structures,this review surveys their building blocks and topologies.Specifically,the frameworks are classified based on the dimensions of their components(building blocks),namely,discrete building blocks and one-dimensional infinite building blocks.For the first category,the materials are further divided into collections of two-and three-dimensional networks based on their topologies.For the second category,the recently emerging MCOFs with woven structures are covered.Finally,the state-of-the-art in MCOF and CMOF chemistry has been laid out for promising avenues in future developments. 关键词：metal–covalent organic frameworks covalent metal-organic frameworks TOPOLOGY building block

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Structural survey of metal-covalent organic frameworks and covalent metal-organic frameworks

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