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Recent advances in visible light-mediated chemical transformations of enaminones

查看全文 作  者:Yu [1,2]Han;Liyun [1]Zhou;Chengyu [2]Wang;Shangti [3]Feng;Rong [2]Ma;Jie-Ping [1]Wan 高影响力作者 机构地区:[1]College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330022,China;[2]School of Chemistry and Chemical Engineering,Linyi University,Linyi 276000,China;[3]Linyi Sanfeng Chemical Co.,Ltd.,Linyi 276000,China高影响力机构 出  处:《Chinese Chemical Letters》索引2024年第35卷第2期,共12页高影响力期刊 基  金:the National Natural Science Foundation of China(No.21702088);the Natural Science Foundation of Shandong Province(No.ZR2022MB130)for the financial support. 摘  要:Enaminones,which possesses both the nucleophilic enamine as well as electrophilic enone structures,are well known versatile building blocks in organic synthesis.Meanwhile,visible light-mediated reactions have emerged as useful synthetic strategy with enhanced sustainability.Around the last decade,various photochemical transformations of enaminones have been developed to construct cyclic or acyclic compounds.In this review,we describe the recent advances in visible light-mediated chemical transformations of enaminones.Detailed discussion on the reaction mechanism of the related reactions is given to provide guide to the reader.Finally,a summary on the existing challenges and the future outlook towards the development of practical photocatalytic reactions of enaminones is also presented. 关 键 词:ENAMINONE Visible light C-H functionalization C=C bond cleavage CYCLIZATION Multicomponent reactions
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