SYNTHESIS OF NEW POLY (p-PHENYLENEVINYLENE) DERIVATIVES WITH IMPROVED SOLUBILITY

查看全文 作　　者：ZHANG [1]Fuqiang;YIN [1]Shougen;LIU [1]Xiaohang;HUANG [1]Wenqiang;HE [1]Binling 机构地区：[1]The State Key Laboratory of Functional Polymer Materialsfor Adsorption and Separation,Institute of Polymer Chemistry,Nankai University,Tianjin 300071,P.R.China 出　　处：《Chinese Journal of Reactive Polymers》索引2000年第9卷第2期,共9页 基　　金：Natural Science Foundation of Tianjin(No.003602511). 摘　　要：PPV-based copolymers with cyano group in the main chain have been synthesized by Wittig-type polycondensation of alkoxy-substituted dialdehydes and 4,4’-bis(cyanomethyl)-substituted diphenyl ether: [―C6H4―O―C6H4―C(CN)(CH―C6H2(OR)2―C(C(CN)―]n (POPPV). The copolymers are highly soluble in common solvents and their super highly transparent homogeneous thin films can be formed by spin coating directly without heat treatment. The chemical structures are determined by NMR and IR spectroscopys and evaluated using photoluminescence, gel-permeation chromatography (GPC) and DSC (or TGA) methods. The incorporation of ether group into the PPV backbone has an interruption of the main-chain conjugation, that results in the blue-shift of electroluminescence spectra and enhancement the solubility. 关 键 词：PPV Polycondesation Organic electroluminescence SOLUBILITY