Screening of MgO- and CeO_2-Based Catalysts for Carbon Dioxide Oxidative Coupling of Methane to C_(2+) Hydrocarbons

查看全文 作　　者：[1]Istadi;Nor Aishah Saidina [1]Amin

机构地区：[1]Chemical Reaction Engineering Group(CREG),Faculty of Chemical and Natural Resources Engineering,,Univevsiti Teknologi Malaysia,UTM Skudai,Johor Bahru,81310 Malaysia

出　　处：《Journal of Natural Gas Chemistry》索引2004年第13卷第1期,共13页

摘　　要：The catalyst screening tests for carbon dioxide oxidative coupling of methane (CO2-OCM)have been investigated over ternary and binary metal oxide catalysts.The catalysts are prepared by doping MgO-and CeO2-based solids with oxides from alkali(Li2O),alkaline earth (CaO),and transition metal groups (WO3 or MnO).The presence of the peroxide (O2^2-)active sites on the Li2O2,revealed by Raman spectroscopy,may be the key factor in the enhanced performance of some of the Li2O/MgO catalysts.The high reducibility of the CeO2 catalyst,an important factor in the CO2-OCM catalyst activity,may be enhanced by the presence of manganese oxide species. The manganese oxide species increases oxygen mobitity and oxygen vacancies in the CeO2 catalyst.raman and Fourier Transform Infra Red (FT-IR)spectroscopies revealed the presence of lattice vibrations of metal-oxygen bondings and active sites in which the peaks carresponding to the buld crystalline structures of Li2O,CaO,WO2 and MnO are detected.The performance of 5%MnO/15%CaO/CeO2 catalyst is the most potential among the CeO2-based catalysts,although lower than the 2%Li2O/MgO catalyst.The 2%Li2O/MgO catalyst showed the most promising C2+hydrocarbons selectivity and yield at 98.0%and 5.7%,respectively. 关键词：天然气催化剂筛选二氧化碳氧化偶合甲烷氧化镁二氧化铈碳氢化合物

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Screening of MgO- and CeO_2-Based Catalysts for Carbon Dioxide Oxidative Coupling of Methane to C_(2+) Hydrocarbons

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