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| 1 | 中温固体氧化物燃料电池复合阴极La_(1.6)Sr_(0.4)NiO_4-Ce_(0.9)Gd_(0.1)O_(1.9)的制备及性能研究显示文摘0引言
近年来,一些具有电子和氧离子混合传导特性的类钙钛矿型A2BO4复合氧化物成为人们研究的热点材料。这类材料一般属于K2NiF4结构,是由ABO3钙钛矿结构层与AO岩盐层相互交叠而成的层状化合物,由于具有良好的晶体结构、独特的电化学性能以及较高的氧化、还原等催化活性.其在新材料开发方面已得到了高度的重视旧。研究表明,用不同价态的离子调变A位可以达到控制B位过渡金属离子的价态和氧化物的非化学计量氧量的目的。这种结构的材料具有二维特征,从而使该类氧化物具有独特的物理化学性能。到目前为止.有关这类材料的晶体结构和气体催化活性的报道较多.而将其用于固体氧化物燃料电池电极方面的研究却相对较少。同传统的钙钛矿型ABO,氧化物LSM和LSCF电极材料相比较,A2BO4复合氧化物在热化学性能、电化学性能以及氧的扩散和表面交换能力等方面显示了明显的优势.这些都预示着该类材料是一种潜在的中温固体氧化物(IT-SOFC)阴极材料。 | 李强 范勇 孙丽萍 赵辉 霍丽华 高山 Jean-Claude Grenier | 2007 | 无机化学学报2007,23,2: | 10 |
| 2 | Electrochemical ageing study of mixed lanthanum/praseodymium nickelates La2-xPrxNiO4+δ as oxygen electrodes for solid oxide fuel or electrolysis cells显示文摘The chemical and electrochemical stability of lanthanide nickelates La2 NiO4+δ(LNO),Pr2 NiO4+δ(PNO)and their mixed compounds La(2-x)PrxNiO4+δ(LPNOs)with x=0.5,1 or 1.5 is reported.The aim is to promote these materials as efficient electrodes for solid oxide fuel cell(SOFC)and/or solid oxide electrolysis cell(SOEC).La2 NiO4+δand La1.5Pr0.5NiO4+δcompounds are chemically very stable as powders over one month in the temperature range 600-800℃,while the other materials rich in praseodymium progressively decompose into various perovskite-deriving components with additional Pr6 O11.Despite their uneven properties,all these materials are quite efficient and sustainable as electrodes on top of gadolinium doped ceria(GDCBL)//yttrium doped zirconia(8 YSZ)electrolyte,for one month at 700℃without polarization.Under polarization(300 mA·cm-2),the electrochemical performances of LNO,PNO and La1.5Pr0.5NiO4+δ(LP5 NO)quickly degrade in SOFC mode,i.e.for the oxygen reduction reaction,while they show durability in SOEC mode,i.e.for the oxide oxidation reaction. | Vaibhav Vibhu Aurélien Flura Aline Rougier Clément Nicollet Sébastien Fourcade Teresa Hungria Jean-Claude Grenier Jean-Marc Bassat | 2020 | Journal of Energy Chemistry2020,29,7: | 6 |
| 3 | 中温固体氧化物燃料电池阴极材料LaBiMn_2O_6的制备与性能显示文摘采用固相法合成了中温固体氧化物燃料电池(IT-SOFCs)阴极材料La Bi Mn2O6,并利用X射线衍射(XRD)和电化学阻抗谱(EIS)进行表征。结果表明该材料与电解质Ce0.7Bi0.3O1.85(CBO)在1 000℃烧结12 h不发生反应。交流阻抗和直流极化测试结果发现,阴极极化电阻随测试温度的增加而逐渐减小,700℃空气中的极化电阻为0.71Ω·cm2;氧分压测试结果显示,在600~700℃范围内,电极反应的速率控制步骤为电极上发生的电荷转移反应。电极过电位为85 m V时,700℃的阴极电流密度达到216 m A·cm-2,表明La Bi Mn2O6是一种潜在的中温固体氧化物燃料电池(IT-SOFCs)阴极材料。 | 肖辉 孙丽萍 赵辉 霍丽华 Jean-Marc Bassat Aline Rougier Sébastien Fourcade Jean-Claude Grenier | 2015 | 无机化学学报2015,31,6: | 5 |
| 4 | 异色瓢虫不同地理种群的ISSR种群多样性分析(英文)显示文摘异色瓢虫Harmonia axyridis(Pallas)在亚洲地区是一种重要的捕食性天敌昆虫,但是当引入到欧美后,对当地的物种产生了威胁。本文用ISSR技术对两个中国本地种群和一个引入美国的种群进行了种群多样性以及种群分化的分析。8条ISSR引物共扩增出105条带,其中多态性条带比率为96.19%。Nei's多样性指数、Shannon信息指数、多态性条带比率,在中国种群与美国种群中均非常接近,种群分化不明显(G_(st)=0.042)。AMOVA分析显示种群多样性主要来源于种群内部,种群间的基因流非常强(N_m=5.537)。基于Nei's多样性构建的聚类结果显示ISSR是一种快速有效的研究异色瓢虫种群多样性关系的技术。 | 李加慧 GRENIER Simon 苏智慧 庞虹 | 2009 | 环境昆虫学报2009,31,4: | 3 |
| 5 | Pro-gastrin-releasing peptide, neuron specific enolase and chromogranin A as serum markers of small cell lung cancer显示文摘 | Pierre-Jean Lamy Jean Grenier Andrew Kramar Jean-Louis Pujol | 2000 | Lung Cancer2000,,3: | 2 |
| 6 | Antifungal activity of chitosan on two postharvest pathogens of strawberry fruits显示文摘 | Ghaouth A Arul J Grenier J | 1992 | Phytopathology1992,82,: | 2 |
| 7 | 钴掺杂Sr1.5La0.5MnO4的合成及高温电化学性能研究显示文摘采用EDTA-柠檬酸法合成了中温固体氧化物燃料电池阴极材料Sr_(1.5)La_(0.5)Mn_(1-x)Co_xO_4(SLMCOx),并利用粉末X射线衍射(XRD)、X射线光电子能谱(XPS)以及电化学交流阻抗谱(EIS)进行表征。结果表明,该材料与Ce0.9Gd0.1O1.95(CGO)在1 200℃烧结12 h不发生化学反应。随着Co掺入量的增加,氧化物中Mn^(3+)和Co^(2+)含量增多,晶格氧含量降低,晶格畸变率增大。交流阻抗谱(EIS)测试结果显示,钴的掺杂明显降低电极的极化电阻,其中Sr_(1.5)La_(0.5)Mn_(0.7)Co_(0.3)O_4阴极在700℃空气中的极化电阻为0.62Ω·cm^2,明显小于Sr_(1.5)La_(0.5)MnO_4阴极在750℃的极化电阻(1.5Ω·cm^2),表明钴掺杂的Sr_(1.5)La_(0.5)Mn_(1-x)CoxO_4是一种潜在的IT-SOFC阴极材料。 | 范宇航 孙丽萍 霍丽华 赵辉 Jean-Marc Bassat Aline Rougier Sebastien Fourcade Jean-Claude Grenier | 2016 | 无机化学学报2016,32,10: | 2 |
| 8 | The potential of trehalose to replace insect hemolymph in artificial media for Trichogramma dendrolimi (Hymenoptera: Trichogrammatidae)显示文摘昆虫添加剂被显示了改进 Trichogramma 种类的人工的媒介的值,但是同时在主机昆虫的平行文化上维持依赖。在现在的学习, Trichogramma dendrolimi Matsumura 在人工的媒介上从鸡蛋在 vitro 被饲养到成年人与中国橡树 silkmoth Antheraea pernyi 的蛹的 hemolymph 的不同内容(Gu 湩琠敨朠晩吗?? | Xin Lu Shi-Chou Han Li-Ying Li Simon Grenier Patrick De Clercq | 2013 | Insect Science2013,20,5: | 2 |
| 9 | A new distance between two bodies of evidence显示文摘 | Anne-Laure Jousselme Dominic Grenier éloi Bossé | 2001 | Information Fusion2001,,2: | 2 |
| 10 | Clinical use of ultrasound tissue harmonic imaging显示文摘 | TRANQUART F GRENIER N EDER V | 1999 | Ultrasound in Med & Biol1999,25,6: | 2 |
| 11 | Comparative Diagnostic Performances of Auscultation, Chest Radiography, and Lung Ultrasonography in Acute Respiratory Distress Syndrome显示文摘 | Daniel Lichtenstein Ivan Goldstein Eric Mourgeon Philippe Cluzel Philippe Grenier Jean-Jacques Rouby | 2004 | Anesthesiology2004,,1: | 2 |
| 12 | Management of an incidentally discovered puhnonary nodule 显示文摘 | Beigelman-Aubry C Hill C Grenier PA | 2007 | Eur Radiol2007,17,2: | 1 |
| 13 | Marker model and markers of small cell lung cancer:assessing the influence of reversible serum NSE CYFRA21-1 and TPS levels on prognosis显示文摘 | Boher JM Pujol JL Grenier J | 2009 | Br J cancer2009,79,910: | 1 |
| 14 | Cyfra21-1, neuron specific enolase and prognosis of non-small cell lung cancer: Propective study in 621 patients 显示文摘 | Pujol JL Boher JM Grenier J | 2001 | Lung Cancer2001,31,: | 1 |
| 15 | Abdomi-nal muscle response during Curl-ups on both stable and labilesurfaces显示文摘 | VERA-GARCIA F J GRENIER S G MCGILL S M | 2000 | Phys Ther2000,80,6: | 1 |
| 16 | Oxidized - LDL inducemorphological c hanges and increase stiffiiess of endothelial cells显示文摘 | Chouinard J A Grenier G Khalil A | 2008 | Exp Cell Res2008,314,16: | 1 |
| 17 | Cyfra 21-1 , neuron specific enolase and prognosis of non-small cell lung cancer: prospective study in 621 patients显示文摘 | Pujol JL Boher JM Grenier J | 2001 | Lung Cancer2001,31,23: | 1 |
| 18 | Use of XMTM radio satellite signal as a source of opportunity for passive coherent location 显示文摘 | Gill L P Grenier D Chouinard J Y | 2011 | lET Proceeding on Radar Sonar and Navigation2011,5,5: | 1 |
| 19 | Variability of EGRET Gamma-ray sources 显示文摘 | Nolan P L Tompkins W F Grenier I A | 2003 | Astrophys J2003,597,1: | 1 |
| 20 | Immunodiag- nosis of tuberculosis: state of the art显示文摘 | Pinto LM Grenier J Schumacher SG | 2012 | Med Princ Pract2012,21,1: | 1 |