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| 1 | Microstructural Evolution and Mechanical Behaviour of Metastable Cu-Zr-Co Alloys显示文摘Three different CueZreCo alloys, namely Cu40Zr37.5Co22.5, Cu42.5Zr45Co12.5and Cu49Zr49Co2, were obtained by rapid cooling. The microstructure and phase formation of as-cast rods with diameters of 2 mm are compared with those of the respective ingots. An increasing Co content stabilises the B2 CuZr phase and leads to the precipitation of a ternary CueZreCo phase. The variation of the cooling rate affects the size of the B2 dendrites as well as the volume fraction and the morphology of the interdendritic phases. The mechanical properties were determined in compression and all alloys show a certain plastic deformability despite the presence of several binary and ternary intermetallic phases. The deformation mechanisms are discussed on the basis of the microstructures and the constituent phases. | S.Pauly K.Kosiba P.Gargarella B.Escher K.K.Song G.Wang U.Kühn J.Eckert | 2014 | Journal of Materials Science & Technology2014，30，6： | 8 |
| 2 | Plastic deformation of a Zr-based bulk metallic glass fabricated by selective laser melting显示文摘Fully amorphous Zr_(52.5)Cu_(17.9)Ni_(14.6)Al_(10)Ti_(5) bulk metallic glass(BMG) samples with a relative density exceeding 98% were fabricated via selective laser melting(SLM).High fracture stresses of around1700 MPa and a reproducible plastic strain of about 0.5% were obtained for cylindrical SLM samples.The analysis of the observed serrations during compressive loading implies that the shear-band dynamics in the additively manufactured samples distinctly differ from those of the as-cast glass.This phenomenon appears to originate from the presence of uniformly dispersed spherical pores as well as from the more pronounced heterogeneity of the glass itself as revealed by instrumented indentation.Despite these heterogeneities,the shear bands are straight and form in the plane of maximum shear stress.Additive manufacturing,hence,might not only allow for producing large BMG samples with complex geometries but also for manipulating their deformation behaviour through tailoring porosity and structural heterogeneity. | L.Deng K.Kosiba R.Limbach L.Wondraczek U.Kühn S.Pauly | 2021 | Journal of Materials Science & Technology2021，，1： | 2 |
| 3 | Osteogenesis and angiogenesis of a bulk metallic glass for biomedical implants显示文摘Implantation is an essential issue in orthopedic surgery.Bulk metallic glasses(BMGs),as a kind of novel materials,attract lots of attentions in biological field owing to their comprehensive excellent properties.Here,we show that a Zr_(61)Ti_(2)Cu_(25)Al_(12)(at.%)BMG(Zr-based BMG)displays the best cytocompatibility,pronounced positive effects on cellular migration,and tube formation from in-vitro tests as compared to those of commercial-pure titanium and poly-ether-ether-ketone.The in-vivo micro-CT and histological evaluation demonstrate the Zr-based BMG can significantly promote a bone formation.Immunofluorescence tests and digital reconstructed radiographs manifest a stimulated effect on early blood vessel formation from the Zr-based BMG.Accordingly,the intimate connection and coupling effect between angiogenesis and osteogenesis must be effective during bone regeneration after implanting Zr-based BMG.Dynamic gait analysis in rats after implanting Zr-based BMG demonstrates a tendency to decrease the pain level during recovery,simultaneously,without abnormal ionic accumulation and inflammatory reactions.Considering suitable mechanical properties,we provide a realistic candidate of the Zr61Ti2Cu25Al12 BMG for biomedical applications. | K.Sun R.Fu X.W.Liu L.M.Xu G.Wang S.Y.Chen Q.J.Zhai S.Pauly | 2022 | Bioactive Materials2022，7，2： | 1 |
| 4 | Plastic Flow of a Cu_(50)Zr_(45)Ti_5 Bulk Metallic Glass Composite显示文摘By modifying the cooling rate, a Cu50Zr45Ti5 alloy with various structures was developed. A fully glassy rod and specimens with different sizes and volume fractions of nanocrystals were produced. The relationship between the structure and mechanical properties of the Cu50Zr45Ti5 alloy was investigated. The different structures result in a transition of the deformation mechanism from being dominated by shear banding to being governed by dislocation action accompanied by shear band formation. These different plastic deformation mechanisms were discussed in the framework of self-organized critical behavior. | G.Wang S.Pauly S.Gorantla N.Mattern J.Eckert | 2014 | Journal of Materials Science & Technology2014，30，6： | 0 |
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