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| 1 | 硫酸溶液中1,1′-硫代羰基二咪唑在碳钢上的吸附及缓蚀影响和碘离子的增强效应(英文)显示文摘The inhibition effect of 1,1′-thiocarbonyldiimidazole (TCDI) on the corrosion behaviors of mild steel (MS) in 0.5 mol·L-1 H2SO4 solution was studied with the help of potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and linear polarization resistance (LPR) techniques. The effect of immersion time on the inhibition effect of TCDI was also investigated over 72 h. For the long-term tests, hydrogen evolution with immersion time (VH2-t) was measured in addition to the three techniques already mentioned. The thermodynamic parameters, such as adsorption equilibrium constant (Kads) and adsorption free energy (△Gads) values, were calculated and discussed. To clarify inhibition mechanism, the synergistic effect of iodide ion was also investigated. The potential of zero charge (PZC) of the MS was studied by electrochemical impedance spectroscopy method, and a mechanism of adsorption process was proposed. It was demonstrated that inhibition efficiency increased with the increase in TCDI concentration and synergistically increased in the presence of KI. The inhibition efficiency was discussed in terms of adsorption of inhibitor molecules on the metal surface and protective film formation. | SOLMAZ R MERT M. E KARDA■ G YAZICI B ERBL M | 2008 | 物理化学学报2008，24，7： | 4 |
| 2 | Investigation of the inhibition effect of 5-((E)-4-phenylbuta-1,3-dienylideneamino)-1,3,4-thiadiazole-2-thiol Schiff base on mild steel corrosion in hydrochloric acid显示文摘 | SOLMAZ R | | 0，，： | 1 |
| 3 | Adsorption and corrosion inhibition effect of 2-((5-mercapto-l,3,4-thiadiazol-2-ylimino) methyl) phenol Schiff base on mild steel 显示文摘 | SOLMAZ R ALTUNBAS E KARDAS G | 2011 | Materials Chemistry and Physics2011，125，： | 1 |
| 4 | Adsorption and corrosion inhibition effect of 2-((5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl)phenol Schiffbase on mild steel显示文摘 | SOLMAZ R ALTUNBAS E KARDAS G | | 0，，： | 1 |
| 5 | Experimental and theo- retical studies of thiazoles as corrosion inhibitors for mild steel in sulphurie acid solution 显示文摘 | Doner A Solmaz R Ozcan M | 2011 | Corros Sei2011，53，： | 1 |
| 6 | The stability of hy- drogen evolution activity and corrosion behavior of NiCu coatings with long-term electrolysis in alkaline solution 显示文摘 | SOLMAZ R OUML N A KARADA G | 2009 | International Journal of Hydrogen Energy2009，34，5： | 1 |
| 7 | A methodology for the design of robust rollover prevention controllers for automotive vehicles with active steering显示文摘 | SOLMAZ S CORLESS M SHORTEN R | 2007 | International Journal of Control2007，80，11： | 1 |
| 8 | Experimental andtheoretical studies of thiazoles as corrosion inhibitors formild steel in sulphuric acid solution显示文摘 | Doner A Solmaz R ozcan M | 2011 | Corrosion Science2011，53，9： | 1 |
| 9 | Experimental and Theoretical Studies of Thiazoles as Corrosion Inhibitors for Mild Steel in Sulphuric Scid Solution显示文摘 | Dfiner A Solmaz R Ozcan M | 2011 | Corros Sci2011，53，9： | 1 |
| 10 | Electrochemical deposition and characterization of NiFe coatings as electrocatalytic materials for alkaline water electrolysis 显示文摘 | SOLMAZ R KARDAS G | 2009 | Electrochimica Acta2009，54，14： | 1 |
| 11 | Clinical features and comorbidity of social phobics in Turkey显示文摘 | Gokalp PG Tukel R Solmaz D | 2001 | Eur Psychiatry2001，16，2： | 1 |
| 12 | Investigation of adsorp- tion and inhibitive effect of 2 - mercaptothiazoline on corro- sion of mild steel in hydrochloric acid media 显示文摘 | Solmaz R Kardas G Culha M | 2008 | Electro- chim Acta2008，53，： | 1 |
| 13 | I)eve- lopment and optimization of solid lipid nanoparticles of amikacin by central composite design 显示文摘 | JALEH V SOLMAZ G MOHAMMAD R K el al | 2010 | J Lipos Res2010，20，2： | 1 |
| 14 | Copper/polypyrrole multilayer coating for 7075 aluminum alloy protection显示文摘 | MERT B D SOLMAZ R KARDAS G | 2011 | Progress in Organic Coatings2011，72，4： | 1 |
| 15 | Investigation of Adsorption and Corrosion Inhibition of Mild Steel in Hydrochloric Acid Solution by 5-(4-Dimethylaminobenzylidene) Rhodanine显示文摘 | SOLMAZ R | 2014 | Corrosion Science2014，79，： | 1 |
| 16 | Hydrogen evolution and corrosion performance of NiZn coatings 显示文摘 | SOLMAZ R KARDAS G | 2007 | Energy Conversion and Management2007，48，2： | 1 |
| 17 | Adsorption and corrosion inhibitive properties of 2-amino-5-mercapto-1,3,4-thiadiazole on mild steel in hydrochloric acid media显示文摘 | Solmaz R Karda G | 2008 | Colloids and Surface2008，312，1： | 1 |
| 18 | Clinical features and co-morbidity of social phobics in Turkey显示文摘 | Gokalp PG Tukel R Solmaz D | 2001 | Eur Psychiatry2001，16，： | 1 |
| 19 | The Investiga- tion of Synergistic Inhibition Effect of Rhodanine and Iodide Ion on the Corrosion of Copper in Sulphuric Acid Solution 显示文摘 | SOLMAZ R AHIN E A DONER A | 2011 | Corrosion Science2011，53，10： | 1 |
| 20 | Copper/Poly- pyrrole Multilayer Coating for 7075 Aluminum Alloy Protec- tion 显示文摘 | MERT B D SOLMAZ R KARDAS G | 2011 | Progress in Organic Coatings2011，72，： | 1 |
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