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1篇 您的检索式:作者名="Sandip RATHOD"
    题名 作者 年代 出处 被引量
1纳米Ce_1Mg_xZr_(1-x)O_2固体多相催化剂的制备、表征及催化合成四氢苯并[b]吡喃衍生物的性能(英文)显示文摘A series of Ce1MgxZr1-xO2 mixed metal oxides with different molar ratios were prepared by simple co-precipitation and were characterized by X-ray diffraction,infrared spectroscopy,scanning electron microscopy,energy dispersive spectroscopy,temperature-programmed desorption of CO2,and N2 adsorption techniques.The prepared materials were tested for catalytic activity by the synthesis of tetrahydrobenzo[b]pyran derivatives using a three component reaction(aromatic aldehydes,malononitrile,and dimedone) in an ethanol medium.The best catalytic activity was obtained with Ce1Mg0.6Zr0.4O2.The particle size or crystallite size was estimated using the Debye-Scherrer equation.The addition of magnesium oxide into the ceria-zirconia lattice resulted in the formation of nanosized particles ranging from 5.41 to 9.78 nm.This work describes the catalytic behavior of magnesium oxide in mixed metal oxide systems.Sandip RATHOD Balasaheb ARBAD Machhindra LANDE 2010催化学报2010,31,6:3
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