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| 1 | Ni/Al_2O_3 catalysts for CO methanation: Effect of Al_2O_3 supports calcined at different temperatures显示文摘The correlation between phase structures and surface acidity of Al2O3 supports calcined at different temperatures and the catalytic performance of Ni/Al2O3 catalysts in the production of synthetic natural gas(SNG) via CO methanation was systematically investigated. A series of 10 wt% NiO/Al2O3 catalysts were prepared by the conventional impregnation method, and the phase structures and surface acidity of Al2O3 supports were adjusted by calcining the commercial γ-Al2O3 at different temperatures(600–1200 C). CO methanation reaction was carried out in the temperature range of 300–600 C at different weight hourly space velocities(WHSV = 30000 and 120000 mL·g-1h-1) and pressures(0.1 and 3.0 MPa). It was found that high calcination temperature not only led to the growth in Ni particle size, but also weakened the interaction between Ni nanoparticles and Al2O3 supports due to the rapid decrease of the specific surface area and acidity of Al2O3 supports. Interestingly, Ni catalysts supported on Al2O3 calcined at 1200 C(Ni/Al2O3-1200) exhibited the best catalytic activity for CO methanation under different reaction conditions. Lifetime reaction tests also indicated that Ni/Al2O3-1200 was the most active and stable catalyst compared with the other three catalysts, whose supports were calcined at lower temperatures(600, 800 and 1000 C). These findings would therefore be helpful to develop Ni/Al2O3 methanation catalyst for SNG production. | Jiajian Gao Chunmiao Jia Jing Li Meiju Zhang Fangna Gu Guangwen Xu Ziyi Zhong Fabing Su | 2013 | Journal of Energy Chemistry2013，22，6： | 16 |
| 2 | Rambutan-like hierarchically heterostructured CeO2-CuO hollow microspheres: Facile hydrothermal synthesis and applications显示文摘层次地空范围具有为由于他们的唯一的结构的特征和性质的大量应用的大兴趣的 heterostructured。然而,有为大规模上的混合转变金属氧化物的高度特定的形态学的明确的空范围的制造仍然保持挑战性。在这个工作,一致像红毛丹的 heterostructured CeO 2-CuO 有积木经由一个灵巧的热水的方法被准备的界面的地点和 nanorods 和 nanoparticles 由锻烧跟随了的众多的 copper-ceria 的空 microspheres。重要地,这条途径能乐意地被扩大规模并且对各种各样的基于 CuO 的混合金属氧化物的合成适用复杂空范围。同样准备的 CeO 2-CuO 当主要由于小主要 nanoparticle 成分,为 supercapacitors 并且作为为 Rochow 反应的基于 Cu 的催化剂的电极材料高出现,空红毛丹两个都展出优异性能众多的内部 heterostructures 的区域,和形成。 | Yongjun Ji Zheying Jin Jing Li Yu Zhang Hezhi Liu Laishun Shi Ziyi Zhong Fabing Su | 2017 | Nano Research2017，10，2： | 4 |
| 3 | One-dimensional Cu-based catalysts with layered Cu-Cu20-CuO walls for the Rochow reaction显示文摘 | Jing Li Zailei Zhang Yongjun Ji Zheying Jin Shanying Zou Ziyi Zhong Fabing Su | 2016 | Nano Research2016，9，5： | 4 |
| 4 | Coking-resistant Ni-ZrO_2/Al_2O_3 catalyst for CO methanation显示文摘Highly coke-resisting Zr O2-decorated Ni/Al2O3 catalysts for CO methanation were prepared by a two-step process. The support was first loaded with Ni O by impregnating method and then modified with Zr O2 by deposition-precipitation method(IM-DP). Nitrogen adsorptiondesorption, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, H2 temperatureprogrammed reduction and desorption, NH3temperature-programmed desorption, and zeta potential analysis were employed to characterize the samples. The results revealed that, compared with the catalysts with the same composition prepared by co-impregnation(CI) and sequential impregnation(SI) methods, the Ni/Al2O3 catalyst prepared by IM-DP showed much enhanced catalytic performance for syngas methanation under the condition of atmospheric pressure and a high weight hourly space velocity of 120000 m L g-1 h-1. In a 80 h life time test under the condition of 300–600°C and 3.0 MPa, this catalyst showed high stability and resistance to coking, and the amount of deposited carbon was only 0.4 wt%. On the contrary, the deposited carbon over the catalyst without Zr O2 reached 1.5 wt% after a 60 h life time test. The improved catalytic performance was attributed to the selective deposition of Zr O2 nanoparticles on the surface of Ni O rather than Al2O3, which could be well controlled via changing the electrostatic interaction in the DP procedure. This unique structure could enhance the dissociation of CO2 and generate surface oxygen intermediates, thus preventing carbon deposition on the Ni particles in syngas methanation. | Qing Liu Fangna Gu Jiajian Gao Huifang Li Guangwen Xu Fabing Su | 2014 | Journal of Energy Chemistry2014，23，6： | 4 |
| 5 | Converting industrial waste contact masses into effective multicomponent copper-based catalysts for the Rochow process显示文摘 | Hezhi Liu Yongjun Ji Yongxia Zhu Guangna Wang Xueguang Wang Ziyi Zhong Fabing Su | 2018 | Particuology2018，16，2： | 2 |
| 6 | Single-atom Sn-Zn pairs in CuO catalyst promote dimethyldichlorosilane synthesis显示文摘Single-atom catalysts are of great interest because they can maximize the atom-utilization efficiency and generate unique catalytic properties;however,much attention has been paid to single-site active components,rarely to catalyst promoters.Promoters can significantly affect the activity and selectivity of a catalyst,even at their low concentrations in catalysts.In this work,we designed and synthesized CuO catalysts with atomically dispersed co-promoters of Sn and Zn.When used as the catalyst in the Rochow reaction for the synthesis of dimethyldichlorosilane,this catalyst exhibited much-enhanced activity,selectivity and stability compared with the conventional CuO catalysts with promoters in the form of nanoparticles.Density functional theory calculations demonstrate that single-atomic Sn substitution in the CuO surface can enrich surface Cu vacancies and promote dispersion of Zn to its atomic levels.Sn and Zn single sites as the co-promoters cooperatively generate electronic interaction with the CuO support,which further facilitates the adsorption of the reactant molecules on the surface,thereby leading to the superior catalytic performance. | Qi Shi Yongjun Ji Wenxin Chen Yongxia Zhu Jing Li Hezhi Liu Zhi Li Shubo Tian Ligen Wang Ziyi Zhong Limin Wang Jianmin Ma Yadong Li Fabing Su | 2020 | National Science Review2020，7，3： | 2 |
| 7 | Morphology-dependent catalytic properties of nano- cupric oxides in the Rochow reaction显示文摘四种 CuO 催化剂与控制得好像叶子(L-CuO ) ,象花(F-CuO ) , sea-urchin-like (U-CuO ) ,并且像燕麦片(O-CuO ) 形态学被各种各样的 chelating ligands 帮助的一个灵巧的降水方法综合。高分辨率的传播电子显微镜学和快 Fourier 转变显示的红外线的光谱学 L-CuO, F-CuO, U-CuO,和 O-CuO 的主导的水晶方面是 { 001 } , { 110 } , { 001 } ,并且 { 110 } ,以及 { 001 } 并且 { 110 } 分别地。当为 Rochow 反应测试了时,他们的催化表演依赖于他们的结构,这被发现。在四 CuO 催化剂之中, L-CuO 展出了最好的催化性质,与为氧和最高的 reducibility 的最强壮的吸附能力一起,它主要因为它的大部分暴露了 { 001 } 方面和大特定的表面区域。另外, Cu 3 Si 合金阶段,是在 Si 表面的反应区域产生了的最重要的反应中介,为不同催化剂被测量。基于调查结果,详细反应机制被建议。这个工作证明氧化物催化剂的那控制形状的合成能是有效策略设计并且发展有效催化剂。 | Yu Zhang Yongjun Ji Jing Li Hezhi Liu Xiao Hu Ziyi Zhong Fabing Su | 2018 | Nano Research2018，11，2： | 2 |
| 8 | Ordered mesoporous Cu-Ca-Zr:A superior catalyst for direct synthesis of methyl formate from syngas显示文摘It is still a big challenge to obtain both highly active and stable Cu-based catalysts for direct synthesis of methyl formate(MF)from syngas.To address the issue,we have designed and synthesized a series of ternary Cu-Ca-Zr catalysts,namely,the ordered mesoporous Cu-Ca-Zr catalyst prepared by one-pot evaporation-induced self-assembly(EISA)method,and the supported CuO/CaO-ZrO_(2)catalysts by impregnating with copper precursor or by immobilizing copper nanoparticles.In the latter two catalysts,the ordered mesoporous CaO-ZrO_(2)support was also prepared by the EISA method.The catalysts were characterized by techniques such as ICP,XRD,TEM,N2 isotherm adsorption-desorption,XPS and H2-TPR,and used for direct synthesis of MF.The results indicated that the catalyst prepared by onepot EISA method,in which the CuO species are highly dispersed in frame of CaO-ZrO_(2),exhibits much better activity and stability as compared with the other two catalysts with most of CuO located on the outer surface of the CaO-ZrO_(2)support,because the former has a higher specific surface area,enhanced synergistic effect and stronger interaction between the CaO-ZrO_(2)support and CuO active constituent. | Jiahao Zhuang Bin Lu Fangna Gu Ziyi Zhong Fabing Su | 2018 | Carbon Resources Conversion2018，1，2： | 2 |
| 9 | A reinforced study on the syn- thesis of microporous titanosilicate ETS-10 显示文摘 | Lv Lu Su Fabing Zhao X S | 2004 | Micro- porous and Mesoporous Mater2004，76，： | 1 |
| 10 | Prep- aration and characterization of PtRu nanoparticles sup- ported on nitrogen-doped porous carbon for electrooxi- dation of methanol 显示文摘 | LIU Zhaolin SU Fabing ZHANG Xinhui | 2011 | ACS Applied Materials & In- terfaces2011，3，10： | 1 |
| 11 | Synthesis and characterization of microporous titanosilicate ETS-10 with different titanium precursors显示文摘 | Lv Lu Su Fabing Zhao X S | 2006 | J Porous Mater2006，3，： | 1 |
| 12 | Solid-state synthesis of Li[Li_(0.2)Mn_(0.56)Ni_(0.16)Co_(0.08)]O_2 cathode materials for lithium-ion batteries显示文摘Layered Li|Li_(0.2)Mn_(0.56)Ni_(0.16)Co_(0.08]O_2 cathode materials were synthesized via a solid-state reaction for Liion batteries,in which lithium hydroxide monohydrate,manganese dioxide,nickel monoxide,and cobalt monoxide were employed as metal precursors.To uncover the relationship between the structure and electrochemical properties of the materials,synthesis conditions such as calcination temperature and time as well as quenching methods were investigated.For the synthesized Li[Li_(0.2)Mn_(0.56)Ni_(0.16)Co_(0.08)]O_2materials,the metal components were found to be in the form of Mn^(4+),Ni^(2+),and Co^(3+),and their molar ratio was in good agreement with stoichiometric ratio of 0.56:0.16:0.08.Among them,the one synthesized at 800 C for 12 h and subsequently quenched in air showed the best electrochemical performances,which had an initial discharge specific capacity and coulombic efficiency of 265.6 mAh/g and 84.0%,respectively,and when cycled at 0.5,1,and 2C,the corresponding discharge specific capacities were 237.3,212.6.and 178.6 mAh/g,respectively.After recovered to 0.1 C rate,the discharge specific capacity became259.5 mAh/g and the capacity loss was only 2.3% of the initial value at 0.1 C.This work suggests that the solid-state synthesis route is easy for preparing high performance Li[Li_(0.2)Mn_(0.56)Ni_(0.16)Co_(0.08)]O_2 cathode materials for Li-ion batteries. | Wenjuan Hao Hanhui Zhan Han Chen Yanhong Wang Qiangqiang Tan Fabing Su | 2014 | Particuology2014，12，4： | 1 |
| 13 | Competitive adsorption of Pb2+,Cu2+,and Cd2+ ions on microporous titanosilicate ETS-10显示文摘 | Lu Lv Mei Peng Hor Fabing Su | 2005 | Colloid and Interface Science2005，，287： | 1 |
| 14 | Nickel catalysts supported on barium hexaaluminate for enhanced CO methanation显示文摘 | Gao Jiajian Jia Chunmiao Li Jing Gu Fangna Xu Guangwen Zhong Ziyi Su Fabing | 2012 | Industrial & Engineering Chemistry Research2012，51，10： | 1 |
| 15 | Sulfur poisoning resistant mesoporous Mn-base catalyst for low-temperature SCR of NO with NH3显示文摘 | Yu Jian Guo Feng Wang Yingli Zhu Jianhong Liu Yunyi Su Fabing Gao Shiqiu Guangwen Xu | | 0，，： | 1 |
| 16 | Conjugated microporous poly(aryleneethynylene)networks显示文摘 | Jiang Jiaxing Su Fabing Trewin Abbie | 2007 | Ange- wandte Chemie International Edition2007，119，45： | 1 |
| 17 | Hydrogenolysis of cellulose to C4–C7 alcohols over bi-functional CuO–MO/Al 2 O 3 (M=Ce, Mg, Mn, Ni, Zn) catalysts coupled with methanol reforming reaction显示文摘 | Yanhua Wu Fangna Gu Guangwen Xu Ziyi Zhong Fabing Su | 2013 | Bioresource Technology2013，，： | 1 |
| 18 | A general bottom-up synthesis of CuO-based trimetallic oxide mesocrystal superstructures for efficient catalytic production of trichlorosilane显示文摘Mesocrystals, the non-classical crystals with highly ordered nanoparticle superstructures, have shown great potential in many applications because of their newly collective properties. However, there is still a lack of a facile and general synthesis strategy to organize and integrate distinct components into complex mesocrystals, and of reported application for them in industrial catalytic reactions. Herein we report a general bottom-up synthesis of CuO-based trimetallic oxide mesocrystals (denoted as CuO-M1Ox-M2Oy, where M1 and M2 = Zn, In, Fe, Ni, Mn, and Co) using a simple precipitation method followed by a hydrothermal treatment and a topotactic transformation via calcination. When these mesocrystals were used as the catalyst to produce trichlorosilane (TCS) via Si hydrochlorination reaction, they exhibited excellent catalytic performance with much increased Si conversion and TCS selectivity. In particular, the TCS yield was increased 19-fold than that of the catalyst-free process. The latter is the current industrial process. The efficiently catalytic property of these mesocrystals is attributed to the formation of well-defined nanoscale heterointerfaces that can effectively facilitate the charge transfer, and the generation of the compressive and tensile strain on CuO near the interfaces among different metal oxides. The synthetic approach developed here could be applicable to fabricate versatile complicated metal oxide mesocrystals as novel catalysts for various industrial chemical reactions. | Hezhi Liu Yongjun Ji Jing Li Yu Zhang Xueguang Wang Haijun Yu Dingsheng Wang Ziyi Zhong Lin Gu Guangwen Xu Yadong Li Fabing Su | 2020 | Nano Research2020，13，10： | 1 |
| 19 | Copolymer-controlled homogeneous precipitation for the synthesis of porous microfibers of alumina 显示文摘 | BAI Peng SU Fabing WU Pingping | 2007 | Langmuir2007，23，8： | 1 |
| 20 | Synthesis and characterization of rnicroporous carbons templated by ammonium-form zeolite Y显示文摘 | Su Fabing Zhao X S Lv Lu | 2004 | Carbon2004，42，： | 1 |
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