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| 1 | Three-dimensional-printed individualized porous implants:A new“implant-bone”interface fusion concept for large bone defect treatment显示文摘Bone defect repairs are based on bone graft fusion or replacement.Current large bone defect treatments are inadequate and lack of reliable technology.Therefore,we aimed to investigate a simple technique using three-dimensional(3D)-printed individualized porous implants without any bone grafts,osteoinductive agents,or surface biofunctionalization to treat large bone defects,and systematically study its long-term therapeutic effects and osseointegration characteristics.Twenty-six patients with large bone defects caused by tumor,infection,or trauma received treatment with individualized porous implants;among them,three typical cases underwent a detailed study.Additionally,a large segmental femur defect sheep model was used to study the osseointegration characteristics.Immediate and long-term biomechanical stability was achieved,and the animal study revealed that the bone grew into the pores with gradual remodeling,resulting in a long-term mechanically stable implant-bone complex.Advantages of 3D-printed microporous implants for the repair of bone defects included 1)that the stabilization devices were immediately designed and constructed to achieve early postoperative mobility,and 2)that osseointegration between the host bone and implants was achieved without bone grafting.Our osseointegration method,in which the“implant-bone”interface fusion concept was used instead of“bone-bone”fusion,subverts the traditional idea of osseointegration. | Teng Zhang Qingguang Wei Hua Zhou Zehao Jing Xiaoguang Liu Yufeng Zheng Hong Cai Feng Wei Liang Jiang Miao Yu Yan Cheng Daoyang Fan Wenhao Zhou Xinhong Lin Huijie Leng Jian Li Xinyu Li Caimei Wang Yun Tian Zhongjun Liu | 2021 | Bioactive Materials2021，6，11： | 9 |
| 2 | Road Impacts on Spatial Patterns of Land Use and Landscape Fragmentation in Three Parallel Rivers Region,Yunnan Province,China显示文摘The structure and function of network is a central issue in landscape ecology.Road networks with hierarchical structure are crucial for understanding landscape dynamics.In this study,we compared the distribution of national road,provincial road,county road and rural road in the Three Parallel Rivers Region(TPRR)in Yunnan Province of China,and estimated the effect of roads(and other factors)on the spatial patterns of land use and land cover with logistic regression.In addition,we analyzed the land use and land cover change(LUCC)and landscape fragmentation in 1989–2005 along a buffer zone of the primary traffic corridor,national road G214.The results showed that,county and rural roads had much higher percentage of length extending into more natural habitats at higher elevation and steeper slope,compared with the higher level roads in this region.While the distributions of natural land cover types were dominated by environmental factors,human land use types i.e.,building land and farmland types were significantly related with roads,linking more closely with lower level roads.The LUCC dynamics(1989–2005)of the G214 buffer zone showed a general trend of land transformation from conifer forests and valley arid shrubs to building land and farmland,and from ice and snow to alpine shrubs and forests.With the length of G214 unchanged during the time,the overall landscape pattern changed little in the buffer zone,but habitat fragmentation and area decrease had occurred for the natural vegetation types,in contrast to patch mergence and expansion of human land use types,and landscape fragmentation was intensified above 2500 m a.s.l.but declined below the elevation.The results indicated the dynamics of landscape composition and patch type level distribution in spite of the stability of the overall landscape pattern,and implied the potential role of roads,especially the low level roads on landscape changes. | LIANG Jun LIU Ye YING Lingxiao LI Peng XU Yue SHEN Zehao | 2014 | Chinese Geographical Science2014，24，1： | 8 |
| 3 | Community assemblage of free-living diazotrophs along the elevational gradient of Mount Gongga显示文摘Mountain systems are unique for studying the responses of species distribution and diversity to environmental changes along elevational gradients.It is well known that free-living diazotrophic microorganisms are important to nitrogen cycling in mountain systems.However,the elevational patterns of free-living diazotrophs and the underlying ecological processes in controlling their turnover along broader gradients are less well documented.Here,we investigated the pattern of diazotrophic diversity along the elevational gradient(1800 m-4100 m)in Mount Gongga of China.The results showed that the α-diversity of diazotrophs did not change with the elevation from 1800 m to 2800 m,but decreased at elevations above 3000 m.Such diversity pattern was driven mainly by soil total carbon,nitrogen,and plant richness.Various diazotrophic taxa showed differential abundance-elevation relationships.Ecological processes determining diazotrophic community assemblage shift along the elevations.Deterministic processes were relatively stronger at both low and high elevations,whereas stochastic processes were stronger at the middle elevation.This study also suggested a strong relationship among aboveground plants and diazotrophs,highlighting their potential interactions,even for free-living diazotrophs. | Yansu Wang Chaonan Li Zehao Shen Junpeng Rui Decai Jin Jiabao Li Xiangzhen Li | 2019 | Soil Ecology Letters2019，1，3： | 8 |
| 4 | The Medium Energy X-ray telescope (ME) onboard the Insight-HXMT astronomy satellite显示文摘The Medium Energy X-ray telescope(ME) is one of the three main telescopes on board the Insight hard X-ray modulation telescope(Insight-HXMT) astronomy satellite. ME contains 1728 pixels of Si-PIN detectors sensitive in 5-30 ke V with a total geometrical area of 952 cm^2. The application specific integrated circuit(ASIC) chip, VA32TA6, is used to achieve low power consumption and low readout noise. The collimators define three kinds of field of views(FOVs) for the telescope, 1°×4°, 4°×4°,and blocked ones. Combination of such FOVs can be used to estimate the in-orbit X-ray and particle background components.The energy resolution of ME is ~3 ke V at 17.8 ke V(FWHM) and the time resolution is 255 μs. In this paper, we introduce the design and performance of ME. | XueLei Cao WeiChun Jiang Bin Meng WanChang Zhang Tao Luo Sheng Yang ChunLei Zhang YuDong Gu Liang Sun XiaoJing Liu JiaWei Yang Xian Li Ying Tan ShaoZhen Liu YuanYuan Du FangJun Lu YuPeng Xu Ju Guan ShuangNan Zhang HuanYu Wang TiPei Li ChengMo Zhang XiangYang Wen JinLu Qu LiMing Song XiaoBo Li MingYu Ge YuPeng Zhou ShaoLin Xiong Shu Zhang YongJie Zhang ZeHao Cheng Fei Zhang MaoShun Li XiaoHua Liang Min Gao EnBo Yang XiaoHang Liu HongWei Liu YiJung Yang Fan Zhang | 2020 | Science China(Physics,Mechanics & Astronomy)2020，63，4： | 5 |
| 5 | Geographical Patterns of Chinese Ethnic Minority Population Composition and Ethnic Diversity显示文摘Ethnicity is a carrier of language and culture.Spatial distribution of ethnic diversity is fundamental for identifying and reconstructing the migration patterns and evolution histories of cultures and languages.Utilizing the Chinese 4th National Census (1990) data,we investigated the specific time geographical patterns of population and diversity of Chinese ethnicminorities.As anticipated,results show that Chineseminorities are chiefly concentrated in dis-tant plateaus and mountains in the southwest,northwest and northeast of China.Further,population density centers of the 10 majorminorities are rather scattered,alternatively dominating at different parts of the country.This study pro-vides a first comprehensive quantitative test on a prevailing notion of 'six plates and three corridors' on the empirical clustering patterns of Chinese ethnicminorities.There are more consistent evidences supporting this notion in the north of China,with the central and southern regions showing more complex patterns,potentially transformed by processes such as migration,fragmentation,and percolation.The results of this study suggest that a geographical ap-proach can provide heuristic and complementary information for better understanding of historical social processes. | SHEN Zehao LI Peng SUN Hongkai PANG Lihua | 2011 | Chinese Geographical Science2011，21，4： | 3 |
| 6 | Auxin response factor 6A regulates photosynthesis,sugar accumulation,and fruit development in tomato显示文摘Auxin response factors(ARFs)are involved in auxin-mediated transcriptional regulation in plants.In this study,we performed functional characterization of SlARF6A in tomato.SlARF6A is located in the nucleus and exhibits transcriptional activator activity.Overexpression of SlARF6A increased chlorophyll contents in the fruits and leaves of tomato plants,whereas downregulation of SlARF6A decreased chlorophyll contents compared with those of wild-type(WT)plants.Analysis of chloroplasts using transmission electron microscopy indicated increased sizes of chloroplasts in SlARF6A-overexpressing plants and decreased numbers of chloroplasts in SlARF6A-downregulated plants.Overexpression of SlARF6A increased the photosynthesis rate and accumulation of starch and soluble sugars,whereas knockdown of SlARF6A resulted in opposite phenotypes in tomato leaves and fruits.RNA-sequence analysis showed that regulation of SlARF6A expression altered the expression of genes involved in chlorophyll metabolism,photosynthesis and sugar metabolism.SlARF6A directly bound to the promoters of SlGLK1,CAB,and RbcS genes and positively regulated the expression of these genes.Overexpression of SlARF6A also inhibited fruit ripening and ethylene production,whereas downregulation of SlARF6A increased fruit ripening and ethylene production.SlARF6A directly bound to the SAMS1 promoter and negatively regulated SAMS1 expression.Taken together,these results expand our understanding of ARFs with regard to photosynthesis,sugar accumulation and fruit development and provide a potential target for genetic engineering to improve fruit nutrition in horticulture crops. | Yujin Yuan Xin Xu Zehao Gong Yuwei Tang Mengbo Wu Fang Yan Xiaolan Zhang Qian Zhang Fengqing Yang Xiaowei Hu Qichen Yang Yingqing Luo Lihua Mei Wenfa Zhang Cai-Zhong Jiang Wangjin Lu Zhengguo Li Wei Deng | 2019 | Horticulture Research2019，6，1： | 3 |
| 7 | Suppression of FHL2 Expression Induces Cell Differentiation and Inhibits Gastric and Colon Carcinogenesis显示文摘 | Jide Wang Yi Yang Harry H.X. Xia Qing Gu Marie C.M. Lin Bo Jiang Ying Peng Guoqing Li Xiaomeng An Yali Zhang Zehao Zhuang Zhenshu Zhang Hsiang Fu Kung Benjamin C.Y. Wong | 2007 | Gastroenterology2007，，3： | 1 |
| 8 | Preoperative carbohydrate loading for elective surgery: a systematic review and meta-analysis显示文摘 | Lun Li Zehao Wang Xiangji Ying Jinhui Tian Tiantian Sun Kang Yi Peng Zhang Zhang Jing Kehu Yang | 2012 | Surgery Today2012，，7： | 1 |
| 9 | Interfacial Characteristics and Mechanical Behavior of Hybrid Manufactured AlSi10Mg–Al6061 Bimetal via Selective Laser Melting and Forging显示文摘Hybrid manufacturing(HM)uses additive manufacturing(AM)techniques to prepare complex or fine structures on traditional processing parts,which can fully utilize the advantages of AM to form complex parts,and the high efficiency and low cost of conventional processing methods in manufacturing regular components.A bimetal material was produced by selective laser melting(SLM)of AlSi10Mg on the deformed Al6061 alloy substrate in this study.Firstly,the interface characteristics of the two alloys were studied.The results show that a metallurgical interface with a thickness of 100–200μm was formed as the result of the Marangoni convection during SLM preparation.In detail,the circular flow in the melt pool at the interface led to the dilution of alloying elements and the change of microstructure.Moreover,a suitable first-layer thickness can eff ectively suppress the hot cracks at the interfacial region.Based on the optimized results,the hybrid manufactured samples with diff erent SLM processed volume ratios(SLM-part)to the substrate were prepared to study the mechanical properties and the deformation behavior of hybrid parts.The results show that the volume ratio of the SLM-part to the substrate had an influence on the strength and the elasto-plastic behavior by aff ecting the distribution of plastic deformation. | Haoxiang Wang Xin Lin Nan Kang Zehao Qin Shuoqing Shi Jiacong Li Weidong Huang | 2022 | Acta Metallurgica Sinica(English Letters)2022，35，3： | 1 |
| 10 | 3D-printed cell-free PCL-MECM scaffold with biomimetic micro-structure and micro-environment to enhance in situ meniscus regeneration显示文摘Despite intensive effort was made to regenerate injured meniscus by cell-free strategies through recruiting endogenous stem/progenitor cells,meniscus regeneration remains a great challenge in clinic.In this study,we found decellularized meniscal extracellular matrix(MECM)preserved native meniscal collagen and glycosaminoglycans which could be a good endogenous regeneration guider for stem cells.Moreover,MECM significantly promoted meniscal fibrochondrocytes viability and proliferation,increased the expression of type II collagen and proteoglycans in vitro.Meanwhile,we designed 3D-printed polycaprolactone(PCL)scaffolds which mimic the circumferential and radial collagen orientation in native meniscus.Taken these two advantages together,a micro-structure and micro-environment dually biomimetic cell-free scaffold was manipulated.This cell-free PCL-MECM scaffold displayed superior biocompatibility and yielded favorable biomechanical capacities closely to native meniscus.Strikingly,neo-menisci were regenerated within PCL-MECM scaffolds which were transplanted into knee joints underwent medial meniscectomy in rabbits and sheep models.Histological staining confirmed neo-menisci showed meniscus-like heterogeneous staining.Mankin scores showed PCL-MECM scaffold could protect articular cartilage well,and knee X-ray examination revealed same results.Knee magnetic resonance imaging(MRI)scanning also showed some neo-menisci in PCL-MECM scaffold group.In conclusion,PCL-MECM scaffold appears to optimize meniscus regeneration.This could represent a promising approach worthy of further investigation in preclinical applications. | Weimin Guo Mingxue Chen Zhenyong Wang Yue Tian Jinxuan Zheng Shuang Gao Yangyang Li Yufeng Zheng Xu Li Jingxiang Huang Wei Niu Shuangpeng Jiang Chunxiang Hao Zhiguo Yuan Yu Zhang Mingjie Wang Zehao Wang Jiang Peng Aiyuan Wang Yu Wang Xiang Sui Wenjing Xu Libo Hao Xifu Zheng Shuyun Liu Quanyi Guo | 2021 | Bioactive Materials2021，6，10： | 1 |
| 11 | SlMYB72 affects pollen development by regulating autophagy in tomato显示文摘The formation and development of pollen are among the most critical processes for reproduction and genetic diversity in the life cycle of f lowering plants.The present study found that SlMYB72 was highly expressed in the pollen and tapetum of tomato f lowers.Downregulation of SlMYB72 led to a decrease in the amounts of seeds due to abnormal pollen development compared with wild-type plants.Downregulation of SlMYB72 delayed tapetum degradation and inhibited autophagy in tomato anther.Overexpression of SlMYB72 led to abnormal pollen development and delayed tapetum degradation.Expression levels of some autophagy-related genes(ATGs)were decreased in SlMYB72 downregulated plants and increased in overexpression plants.SlMYB72 was directly bound to ACCAAC/ACCAAA motif of the SlATG7 promoter and activated its expression.Downregulation of SlATG7 inhibited the autophagy process and tapetum degradation,resulting in abnormal pollen development in tomatoes.These results indicated SlMYB72 affects the tapetum degradation and pollen development by transcriptional activation of SlATG7 and autophagy in tomato anther.The study expands the understanding of the regulation of autophagy by SlMYB72,uncovers the critical role that autophagy plays in pollen development,and provides potential candidate genes for the production of male-sterility in plants. | Mengbo Wu Qiongdan Zhang Guanle Wu Lu Zhang Xin Xu Xiaowei Hu Zehao Gong Yulin Chen Zhengguo Li Honghai Li Wei Deng | 2023 | Horticulture Research2023，10，3： | 0 |
| 12 | An angular blinking jamming method based on electronically controlled corner reflectors显示文摘Passive jamming is believed to have very good potential in countermeasure community.In this paper,a passive angular blinking jamming method based on electronically controlled corner reflectors is proposed.The amplitude of the incident wave can be modulated by switching the corner reflector between the penetration state and the reflection state,and the ensemble of multiple corner reflectors with towing rope can result in complex angle decoying effects.Dependency of the decoying effect on corner reflectors’radar cross section and positions are analyzed and simulated.Results show that the angle measured by a monopulse radar can be significantly interfered by this method while the automatic tracking is employed. | GAN Lin WU Zehao WANG Xuesong LI Jianbing | 2024 | Journal of Systems Engineering and Electronics2024，35，2： | 0 |
| 13 | Sb-Cu alloy cathode with a novel lithiation mechanism of ternary intermetallic formation: Enabling high energy density and superior rate capability of liquid metal battery显示文摘Antimony(Sb) is an attractive cathode for liquid metal batteries(LMBs) because of its high theoretical voltage and low cost.The main obstacles associated with the Sb-based cathodes are unsatisfactory energy density and poor rate-capability.Herein,we propose a novel Sb_(64)Cu_(36)cathode that effectively tackles these issues.The Sb_(64)Cu_(36)(melting point:525℃) cathode presents a novel lithiation mechanism involving sequentially the generation of Li_(2)CuSb,the formation of Li_(3)Sb,and the conversion reaction of Li_(2)CuSb to Li_(3)Sb and Cu.The generated intermetallic compounds show a unique microstructure of the upper floated Li_(2)CuSb layer and the below cross-linked structure with interpenetrated Li_(2)CuSb and Li_(3)Sb phases.Compared with Li_(3)Sb,the lower Li migration energy barrier(0.188 eV) of Li_(2)CuSb significantly facilitates the lithium diffusion across the intermediate compounds and accelerates the reaction kinetics.Consequently,the Li‖Sb_(64)Cu_(36)cell delivers a more excellent electrochemical performance(energy density:353 W h kg^(-1)at 0.4 A cm^(-2);rate capability:0.59 V at 2.0 A cm^(-2)),and a much lower energy storage cost of only 38.45 $ kW h^(-1)than other previously reported Sb-based LMBs.This work provides a novel cathode design concept for the development of high-performance LMBs in applications for large-scale energy storage. | Peng Chu Jie Wang Hongliang Xie Qian Zhang Jiangyuan Feng Zehao Li Zhao Yang Hailei Zhao | 2023 | Journal of Energy Chemistry2023，，3： | 0 |
| 14 | Study on theoretical model for electrical explosion resistivity of Al/Ni reactive multilayer foil显示文摘Al/Ni reactive multilayer foil(RMF)possesses excellent comprehensive properties as a promising substitute for traditional Cu bridge.A theoretical resistivity model of Al/Ni RMF was developed to guide the optimization of EFIs.Al/Ni RMF with different bilayer thicknesses and bridge dimensions were prepared by MEMS technology and electrical explosion tests were carried out.According to physical and chemical reactions in bridge,the electrical explosion process was divided into 5 stages:heating of condensed bridge,vaporization and diffusion of Al layers,intermetallic combination reaction,intrinsic explosion,ionization of metal gases,which are obviously shown in measured voltage curve.Effects of interface and grain boundary scattering on the resistivity of film metal were considered.Focusing on variations of substance and state,the resistivity was developed as a function of temperature at each stage.Electrical explosion curves were calculated by this model at different bilayer thicknesses,bridge dimensions and capacitor voltages,which showed an excellent agreement with experimental ones. | Zehao Wang Tao Wang Pengfei Xue Mingyu Li Qingxuan Zeng | 2024 | Defence Technology(防务技术)2024，32，2： | 0 |
| 15 | Engineering hierarchical metal-organic@metal-DNA heterostructures for combinational tumor treatment显示文摘Development of simple methods for controlled integration of DNA molecules with metal-organic frameworks(MOFs)is important for various biomedical applications,yet remains a challenge.Herein,a simple and general approach to load DNA on the surface of MOFs is developed via one-pot self-assembly of DNA and FeII ions on nanoscale MOFs,resulting in hierarchical core-shell nanostructures of metal-organic@metal-DNA coordination polymers.The strategy enables assembly of DNA molecules on MOFs with ultra-high contents and precise controllability.By incorporation of a chemotherapeutic drug into the Fe-DNA shell,the systems allow to integrate chemotherapy and gene therapy with photodynamic therapy for combinational tumor treatment.Moreover,the hybrid nanostructures enable light-triggered production of cytotoxic singlet oxygen,which further boosts the endosomal escape of the system for an enhanced gene silencing efficacy and thus improved therapeutic outcome.This work highlights a robust approach for the construction of coordination-based drug delivery systems to combat tumor. | Xueyan Feng Bei Liu Zehao Zhou Wei Li Jian Zhao Lele Li Yuliang Zhao | 2023 | Nano Research2023，16，11： | 0 |
| 16 | The Impact of Industrial Policy on Photovoltaic Enterprise Risk Using an LDA Based-Deep Neural Network Model显示文摘The development and utilization of new and renewable resources of energy has become an important layout of the development strategy in China.Photovoltaic industry is an important strategic emerging industry for the development and utilization of new energy in China.Therefore,it is important for the government to make policy to ensure the stable and orderly development of photovoltaic enterprises to accelerate the industrial structure transition in China.This paper collects the policies on photovoltaic industry,and then analyzes the industrial policy with Latent Dirichlet Allocation(LDA).LDA is generally used in document topic label extraction and recommendation system.However,this paper applies it to policy theme analysis to study the impact of policy information flow on the risk of photovoltaic enterprises.Previous studies on photovoltaic enterprise risk examined traditional financial indicators,such as asset-liability Ratio and ROE.However,the textual information in the industrial policy has rarely been studied to quantitatively analyze photovoltaic enterprise risk.In our proposed method,LDA is first used to extract the text features hiding in the text of the industrial policies,and deep neural networks then are trained on the data,which include the text features and traditional numeric features for predict photovoltaic enterprise risk.The experimental results show that the industrial policy of the current quarter has a significant effect on photovoltaic enterprise risk.Compared with this,the industrial policy of last quarter has a weak impact on the photovoltaicenterprise risk.The proposed model is a useful tool for the prediction of the photovoltaic enterprise risk. | Xinye GAN Taiyinghua XU Zehao LI Wei XU Hong ZHAO | 2022 | Journal of Systems Science and Information2022，10，2： | 0 |
| 17 | Transcutaneous auricular vagus nerve stimulation would be an alternative to implantable cervical vagus nerve stimulation in some situation显示文摘Implantable cervical vagus nerve stimulation(i VNS) is a representative and promising neuromodulation.However,the invasive nature restricts its application.Traditional auricular acupuncture treatment has a long history.The auricular branch of the vagus nerve(ABVN) is a branch on the surface of the ear.Some studies demonstrates that transcutaneous auricular vagus nerve stimulation(ta VNS) would achieve similar effects as i VNS.Ta VNS and i VNS share a common anatomical basis and acting mechanism.In this article,we made a comparison between i VNS and ta VNS in indications and efficacy.The recent studies have revealed similar clinical efficacy of ta VNS,ta VNS would expand the indication of i VNS.Highquality clinical evidences are needed before ta VNS become be an alternative of i VNS. | HE Jiakai ZHANG Jinling WANG Yu LI Shaoyuan FANG Jiliang ZHANG Shuai ZHAO Yanan ZHAI Weihang GAO Deqiang LI Ran JIANG Yuhang CHEN Zehao JIA Baohui RONG Peijing | 2023 | Journal of Traditional Chinese Medicine2023，43，3： | 0 |
| 18 | Monocular vision and calculation of regular three-dimensional target pose based on Otsu and Haar-feature AdaBoost classifier显示文摘Using machine vision to identify and sort scattered regular targets is an urgent problem to be solved in automated production lines.This study proposed a three-dimensional(3D)recognition method combining monocular vision and machine learning algorithms.According to the color characteristics of the targets,to convert the original color picture into YCbCr mode and use the 2D Otsu algorithm to perform gray level image segmentation on the Cb channel.Then the Haar-feature training was carried out.The comparison of feature training and Haar method for Hough transform showed that the recognized time of Haar-feature AdaBoost trainer reached 31.00 ms,while its false recognized rate was 3.91%.The strong classifier was formed by weight combination,and the Hough contour transformation algorithm was set to correct the normal vector between plane coordinate and camera coordinate system.The monocular vision system ensured that the field of camera view had not obstructed while the dots were being struck.It was measured and calculated angles between targets and the horizontal plane which coordinate points of the identified plane feature.The testing results were compared with the Otsu and AdaBoost trainer where the prediction and training set have an error of no more than 0.25 mm.Its correct rate can reach 95%.It shows that the Otsu and Haar-feature based on AdaBoost algorithm is feasible within a certain error ranges and meet the engineering requirements for solving the poses of automated regular three-dimensional targets. | Yuanhong Li Hongjun Wang Weiliang Zhou Zehao Xue | 2020 | International Journal of Agricultural and Biological Engineering2020，13，5： | 0 |
| 19 | Interface Engineering and Anion Engineering of Mo-Based Heterogeneous Electrocatalysts for Hydrogen Evolution Reaction显示文摘Development and utilization of hydrogen energy is an effective way to achieve carbon neutrality,only hydrogen production through electrolytic water splitting meets the goal of zero carbon emission.To facilitate the large-scale commercialization of water splitting devices,the development of highly efficient and low-cost catalysts to reduce the energy consumption is essential.MoS_(2)has been regarded as a promising electrocatalyst to replace platinum in hydrogen evolution reaction due to its low price and unique 2D layered structure.However,the poor conductivity and inert basal planes of MoS_(2)limited its wide-spread application.Recently,researches have demonstrated that the conductivity and active sites of MoS_(2)can be improved by heteroatoms doping or constructing of heterogeneous structures.In this review,the recent progress of Mo-based catalysts are summarized centered on MoS_(2)based on interface engineering and anion engineering,including MoS_(2)–MoO_(2),MoS_(2)–Mo_(2)C,MoS_(2)–MoN_(x),MoS_(2)–MoP,and MoS_(2)–MoSe_(2).The preparation method,structure,and performance of the catalysts are introduced and the possible mechanism behind the improved catalytic activity are revealed to give readers an overall comprehension on the progress of the Mo-based electrocatalysts for hydrogen evolution reaction.In addition,an outlook on future opportunities and development directions of Mo-based catalysts are proposed to facilitate the development of Mo-based catalysts for hydrogen production. | Zehao Yin Xuan Liu Siru Chen Tingli Ma Yanqiang Li | 2023 | Energy & Environmental Materials2023，6，1： | 0 |
| 20 | Advanced Strategies for Stabilizing Single‑Atom Catalysts for Energy Storage and Conversion显示文摘Well-defined atomically dispersed metal catalysts(or single-atom catalysts)have been widely studied to fundamentally under-stand their catalytic mechanisms,improve the catalytic efficiency,increase the abundance of active components,enhance the catalyst utilization,and develop cost-effective catalysts to effectively reduce the usage of noble metals.Such single-atom cata-lysts have relatively higher selectivity and catalytic activity with maximum atom utilization due to their unique characteristics of high metal dispersion and a low-coordination environment.However,freestanding single atoms are thermodynamically unstable,such that during synthesis and catalytic reactions,they inevitably tend to agglomerate to reduce the system energy associated with their large surface areas.Therefore,developing innovative strategies to stabilize single-atom catalysts,including mass-separated soft landing,one-pot pyrolysis,co-precipitation,impregnation,atomic layer deposition,and organometallic complexation,is critically needed.Many types of supporting materials,including polymers,have been commonly used to stabilize single atoms in these fabrication techniques.Herein,we review the stabilization strategies of single-atom catalyst,including different synthesis methods,specific metals and carriers,specific catalytic reactions,and their advantages and disadvantages.In particular,this review focuses on the application of polymers in the synthesis and stabilization of single-atom catalysts,including their functions as carriers for metal single atoms,synthetic templates,encapsulation agents,and protection agents during the fabrication process.The technical challenges that are currently faced by single-atom catalysts are summarized,and perspectives related to future research directions including catalytic mechanisms,enhancement of the catalyst loading content,and large-scale implementation are proposed to realize their practical applications. | Wenxian Li Zehao Guo Jack Yang Ying Li Xueliang Sun Haiyong He Sean Li Jiujun Zhang | 2022 | Electrochemical Energy Reviews2022，5，3： | 0 |
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